| Affiliation: | 1. Guizhou University Key Laboratory of Green Chemical and Clean Energy Technology, Guizhou University Engineering Research Centre of Efficient Utilization for Industrial Waste, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang, 550025 Guizhou, P.R. China
These authors contributed equally to this work.;2. Guizhou University Key Laboratory of Green Chemical and Clean Energy Technology, Guizhou University Engineering Research Centre of Efficient Utilization for Industrial Waste, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang, 550025 Guizhou, P.R. China |
| Abstract: | The designs of efficient and inexpensive Pt-based catalysts for methanol oxidation reaction (MOR) are essential to boost the commercialization of direct methanol fuel cells. Here, the highly catalytic performance PtFe alloys supported on multiwalled carbon nanotubes (MWCNTs) decorating nitrogen-doped carbon (NC) have been successfully prepared via co-engineering of the surface composition and electronic structure. The Pt1Fe3@NC/MWCNTs catalyst with moderate Fe3+ feeding content (0.86 mA/mgPt) exhibits 2.26-fold enhancement in MOR mass activity compared to pristine Pt/C catalyst (0.38 mA/mgPt). Furthermore, the CO oxidation initial potential of Pt1Fe3@NC/MWCNTs catalyst is lower relative to Pt/C catalyst (0.71 V and 0.80 V). Benefited from the optimal surface compositions, the anti-corrosion ability of MWCNT, strong electron interaction between PtFe alloys and MWCNTs and the N-doped carbon (NC) layer, the Pt1Fe3@NC/MWCNTs catalyst presents an improved MOR performance and anti-CO poisoning ability. This study would open up new perspective for designing efficient electrocatalysts for the DMFCs field. |
