Preconcentration of copper,cadmium, mercury and lead from sea and tap water samples on a dithiocarbamatecellulose derivative |
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Authors: | RS Shreedhara Murthy Douglas E Ryan |
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Affiliation: | Trace Analysis Research Centre, Chemistry Department, Dalhousie University, Halifax, N.S. B3H4J1 Canada |
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Abstract: | Ethylenediamine, 2,2'-diaminodiethylamine, and triethylenetetramine (trien) were introduced onto microcrystalline cellulose after tosylation. Dithiocarbamate (DTC) groups were introduced by reaction with carbon disulphide. The metal uptake behaviour of these amine- and dithiocarbamate-cellulose derivatives were compared for Cu(II), Cd(II), Pb(II), Hg(II), Co(II), and U(VI). The trien—DTC-cellulose was used to preconcentrate Cu(II), Cd(II), Hg(II), and Pb(II) from sea and tap water. |
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