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改性粉煤灰对燃煤电厂脱硫废水中氯离子的吸附性能
引用本文:刘凌寒,高良敏,张金昕,王硕,包文运,向朝虎,吴晔. 改性粉煤灰对燃煤电厂脱硫废水中氯离子的吸附性能[J]. 电镀与涂饰, 2021, 40(3): 239-245. DOI: 10.19289/j.1004-227x.2021.03.015
作者姓名:刘凌寒  高良敏  张金昕  王硕  包文运  向朝虎  吴晔
作者单位:安徽理工大学地球与环境学院,安徽 淮南 232001;安徽理工大学地球与环境学院,安徽 淮南 232001;安徽理工大学地球与环境学院,安徽 淮南 232001;安徽理工大学地球与环境学院,安徽 淮南 232001;大唐环境产业集团股份有限公司,江苏 南京 211106;大唐环境产业集团股份有限公司,江苏 南京 211106;大唐环境产业集团股份有限公司,江苏 南京 211106
基金项目:中国大唐集团公司科学技术基金资助项目
摘    要:为了将"以废治废"的理念融入实际工业应用中,开展对燃煤电厂固体废弃物粉煤灰改性后在不同条件下进行脱硫废水的吸附实验研究.结果表明,改性粉煤灰的最佳投加量为25 g/L,此时对废水中Cl-的去除率最大,为56%;在45°C和pH为5的条件下,粉煤灰对Cl-的吸附量最大,在反应约280 min时达到吸附平衡.该吸附过程为吸...

关 键 词:脱硫废水  粉煤灰  改性  氯离子  吸附

Adsorbility of modified fly ash to chloride ions in desulfurization wastewater from coal-fired power plant
LIU Linghan,GAO Liangmin,ZHANG Jinxin,WANG Shuo,BAO Wenyun,XIANG Chaohu,WU Ye. Adsorbility of modified fly ash to chloride ions in desulfurization wastewater from coal-fired power plant[J]. Electroplating & Finishing, 2021, 40(3): 239-245. DOI: 10.19289/j.1004-227x.2021.03.015
Authors:LIU Linghan  GAO Liangmin  ZHANG Jinxin  WANG Shuo  BAO Wenyun  XIANG Chaohu  WU Ye
Affiliation:(School of Earth and Environment,Anhui University of Science and Technology,Huainan 232001,China;Datang Environmental Industry Group Co.,Ltd.,Nanjing 211106,China)
Abstract:In order to integrate the concept of"using waste to treat waste"into practical industrial applications,the adsorption of desulfurization wastewater by adsorption with fly ash produced in a coal-fired power plant after modification was studied experimentally under different conditions.The results showed that the optimal dosage of modified fly ash was 25 g/L,where the removal rate of Cl-was as maximum as 56%.The adsorption amount of Cl-was maximum at temperature45℃and pH 5,and the adsorption equilibrium was established after reaction for 280 min under the given conditions.The reaction was endothermic and in line with Langmuir isotherm adsorption model.The phase composition and functional groups of the modified fly ash were changed significantly after adsorption,indicating that the adsorption performance of fly ash was improved after modification.The adsorption was mainly a physical process accompanied with chemical reaction.
Keywords:desulfurization wastewater  fly ash  modification  chloride ion  adsorption
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