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Luminescent Properties of Ca2 Y8 ( SiO4 ) 6O2:Eu3 + Phosphors Prepared by Spray Pyrolysis Process
Authors:Shen Weiying  Lin Jun
Abstract:Using CaCO3, metal oxides (all dissolved by nitric acid) and tetraethoxysilane Si (OC2H5 )4 (TEOS) as the main starting materials, Ca2Y8 (SiO4 )6O2: Eu3 phosphors were synthesized by spray pyrolysis.X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) spectra as well as lifetimes were used to characterize the resulting phosphors.The results of XRD indicated that the 1000 ℃ annealed powders crystallize with the silicate oxyapatite structure.SEM study revealed that the phosphors consist of spherical particles with an average size of about 1 ~ 3 μm.In the crystalline Ca2 Y8 (SiO4)6O2: Eu3 phosphor, the Eu3 shows its characteristic emission corresponding to 5 D0 - 7 FJ ( J = 0, 1,2, 3, 4) transitions, with 5D0 - 7 F2 red emission (613 nm) as the most prominent group, agreeing well with the structure of the host material.
Keywords:silicate oxyapatite  spray pyrolysis  luminescence  europium  spherical phosphor
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