Co-cross-linking of bio-based multi-functional epoxide and bisphenol A diglycidyl ether with 2-ethyl-4-methylimidazole |
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| Authors: | Hisatoyo Morinaga Mayu Sakamoto |
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| Affiliation: | 1. Faculty of Education, Graduate Faculty of Interdisciplinary Research, University of Yamanashi, 4-4-37, Takeda, Kofu, Yamanashi 400-8510, Japan;2. Faculty of Education and Human Sciences, University of Yamanashi, 4-4-37, Takeda, Kofu, Yamanashi 400-8510, Japan |
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| Abstract: | A co-cross-linking reaction of bio-based multi-functional epoxides (1) derived from limonene oxide and bisphenol A diglycidyl ether (BPADE) in the presence of 2-ethyl-4-methylimidazole (EMI) as a cross-linker afforded the corresponding network copolymers (2) having the 10% thermal decomposition temperature (Td10) of 294.4?°C at maximum. Adhesive strength induced by 1, especially tetra-functional epoxide, and BPADE exhibited remarkably higher than that by BPADE alone. |
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| Keywords: | Bio-based polymers Epoxides Cross-linking reaction Limonene |
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