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原油降凝剂的研制与初步应用试验
引用本文:汤建华,徐立群,潘浪胜,陈灏.原油降凝剂的研制与初步应用试验[J].精细石油化工,2001(5):4-7.
作者姓名:汤建华  徐立群  潘浪胜  陈灏
作者单位:浙江大学化学工程研究所
基金项目:本课题得到浙江大学聚合反应工程国家重点实验室的资助,在此谨表示谢意.
摘    要:合成了两个系列的原油降凝剂 ,一个是丙烯酸高碳醇酯和马来酸酐共聚 ,然后用高级脂肪胺胺解 ;另一个是 α 烯烃和马来酸酐共聚 ,然后用高级脂肪胺胺解。添加 1 0 0× 1 0 - 6的此类降凝剂于大庆原油中 ,结合热处理 ,可降低凝固点 1 9~ 2 2℃。讨论了原油的性质、降凝剂的结构及试验条件对降凝效果的影响。加入 1 0 0×1 0 - 6试样到辽河、任丘、新疆、和大庆原油中 ,也有较好的降凝作用 ,表明这些共聚物是适合于高蜡原油的降凝剂

关 键 词:降凝剂  流动性改进剂  含蜡原油  丙烯酸酯  α烯烃  马来酸酐  共聚物  烷基胺
修稿时间:2000年3月3日

SYNTHESIS OF TWO SERIES OF POUR POINT DEPRESSANTS FOR CRUDE OIL AND THEIR PRELIMINARY APPLICATION TESTS
Tang Jianhua,Xu Liqun,Pan Langsheng and Chen Hao.SYNTHESIS OF TWO SERIES OF POUR POINT DEPRESSANTS FOR CRUDE OIL AND THEIR PRELIMINARY APPLICATION TESTS[J].Speciality Petrochemicals,2001(5):4-7.
Authors:Tang Jianhua  Xu Liqun  Pan Langsheng and Chen Hao
Abstract:Two series of pour point depressants (PPD) for crude oils were synthesized. One was the higher alloy acrylate (C 18 and C 18 ~ C 30 )maleic anhydride copolymer aminolyzed by reacting with C 18 ~ C 30 amine, the other was the maleic anhydridealphaolefins copolymer aminolyzed by C 18 ~C 30 amine. Adding 100 ppm of PPD to Daqing crude oil combined with heat treating resulted a pour point depression of 19 to 22 ℃. The effects of crude oil properties, the structure of PPD and the testing conditions on pour point depression were discussed. When samples were added 100 ppm to Liaohe, Renqiu, Xinjiang crude oil, results showed that they have good pour point depressing effects on paraffin rich crude oils.
Keywords:pour point depressant  flow improver  paraffin rich crude oil  acrylate    α  olefin  maleic anhydride  copolymer  alkyl amine
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