| 贫电子环丙烷衍生物与苯硫酚的反应研究 |
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| 引用本文： | 孙汝淑,曹卫国,丁维钰,叶青,高金森.贫电子环丙烷衍生物与苯硫酚的反应研究[J].合成化学,2004,12(4):351-354,J002. |
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| 作者姓名： | 孙汝淑 曹卫国 丁维钰 叶青 高金森 |
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| 作者单位： | 上海大学化学系,上海,200436;上海大学化学系,上海,200436;中国科学院上海有机所金属有机化学国家重点实验室,上海,200032 |
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| 基金项目： | SupportedbytheNationalNaturalScienceFoundationofChina(2 0 172 0 37) |
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| 摘 要： | 顺-1乙酰基-2-对位取代苯基-6，6-二甲基-5，7-二氧-螺-2，5]4，8-辛二酮(1a～ld)与苯硫酚(2)在封管中100℃反应得β-乙酰基-r-苯硫基-r-对位取代苯基丁酸苯硫酯(3a～3d)，当反应物为1a时，还同时得到α-苯硫羰基-β-乙酰基-r-对甲苯基-r-丁酸内酯(4)。
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| 关 键 词： | 顺式-1 2贫电子环丙烷衍生物 多取代丁酸苯硫酯 γ-丁酸内酯 合成 |
Study on the Reaction of Electron-Deficient Cyclopropane Derivatives with Thiophenol |
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| Abstract.Study on the Reaction of Electron-Deficient Cyclopropane Derivatives with Thiophenol[J].Chinese Journal of Synthetic Chemistry,2004,12(4):351-354,J002. |
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| Authors: | Abstract |
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| Abstract: | Cis-1-acetyl-2-p-substitutedphenyl-6,6-dimethyl-5,7-dioxa-spiro-2,5]-4,8-octadiones(1a～1d) reacted with thiophenol(2) in a sealed tube at 100℃ to give phenyl β-acetyl-γ-phenylthio-γ-p-substituted-phenyl-butyrothioates(3a～3d), while 1a as the reactant, α-carbophenylthio-β- acetyl-γ-p-methyl- phenylbutyro-γ-lactone(4) was also obtained. |
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| Keywords: | cis-1 2-cyclopropane derivatives phenyl butyrothioates derivatives γ-butyrolactone synthesis |
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