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WO3对掺铒碲酸盐玻璃光谱性质的影响
引用本文:贾相华,吕树臣,孙江亭,彭鸿雁,张梅恒.WO3对掺铒碲酸盐玻璃光谱性质的影响[J].物理学报,2008,57(9):5978-5982.
作者姓名:贾相华  吕树臣  孙江亭  彭鸿雁  张梅恒
作者单位:(1)哈尔滨师范大学物理系,哈尔滨 150080; (2)牡丹江师范学院物理系,牡丹江 157012
基金项目:超硬材料黑龙江省高校重点建设经费,凝聚态物理黑龙江省重点学科经费和实验室黑龙江省教育厅科学技术研究项目(批准号:10541241)资助的课题.
摘    要:制备了掺铒碲钨酸盐玻璃(80-x)TeO2-(10+x)WO3-8BaO-2Na2O-0.5Er2O3(x=0,5,10,15,20)玻璃,研究了WO3对掺铒碲钨酸盐玻璃的光谱性质. 研究发现:随着WO3含量的增加,Ω4Ω6先增加后减小,受 关键词: 碲钨酸盐玻璃 3+光谱性质')" href="#">Er3+光谱性质 Judd-Offelt理论

关 键 词:碲钨酸盐玻璃  Er3+光谱性质  Judd-Offelt理论
收稿时间:2007-11-20

Effects of WO3 on optical properties of Er3+-doped tungsten-tellurite glasses
Jia Xiang-Hua,Lü Shu-Chen,Sun Jiang-Ting,Peng Hong-Yan,Zhang Mei-Heng.Effects of WO3 on optical properties of Er3+-doped tungsten-tellurite glasses[J].Acta Physica Sinica,2008,57(9):5978-5982.
Authors:Jia Xiang-Hua  Lü Shu-Chen  Sun Jiang-Ting  Peng Hong-Yan  Zhang Mei-Heng
Abstract:Tungsten-tellurite glasses with the molar compositions of (60+x)TeO2-(30-x)WO3-8BaO-2Na2O-0.5Er2O3 (x=0,5,10,15,20) have been prepared. Effects of WO3 on optical properties of Er3+-doped tungsten-tellurite glasses have been discussed. Along with the WO3 content increasing, Ω2 and Ω6 first increase and then decrease, and the stimulated emission cross-section also behaves in like manner, while Ω4 changes contrarily. According to the McCumber theory, the maximum peak of σe is calculate to be 1.00×10-21cm2 at 1.55μm. The maximum FWHM of Er3+ 4I13/24I15/2 emission spectrum is 82nm. In addition, the intensity of upconversion luminescence of the Er3+-doped tungsten-tellurite glasses decreases rapidly with the increasing of WO3 content.
Keywords:tungsten-tellurite glasses  Er3+spectroscopic properties  Judd-Ofelt theory
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