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微波干法制备阳离子淀粉絮凝剂及其应用
引用本文:王琛,陈杰镕,宗刚,陈瑞芬.微波干法制备阳离子淀粉絮凝剂及其应用[J].化工进展,2003,22(11):1217-1221.
作者姓名:王琛  陈杰镕  宗刚  陈瑞芬
作者单位:1. 西安交通大学生命科学与技术学院,西安,710049;西安工程科技学院环境与化工分院,西安,710048
2. 西安交通大学生命科学与技术学院,西安,710049
3. 西安工程科技学院环境与化工分院,西安,710048
4. 西安高新开发区环境监测站,西安,710075
摘    要:以3—氯—2—羟丙基三甲基氯化铵为阳离子醚化剂,天然物质淀粉为原料,微波干法制得季铵型阳离子淀粉絮凝剂。通过正交试验,研究了各种因素对合成的影响,确定了最佳反应条件。结果表明:阳离子醚化剂与淀粉摩尔比0.35、NaOH与阳离子醚化剂摩尔比1.2、微波功率184W、辐射时间5min时,产物相对黏度为3.18,阳离子取代度为0.31。

关 键 词:微波  干法  制备  阳离子淀粉絮凝剂  季铵盐  污水处理  絮凝性能
文章编号:1000-6613(2003)11-1217-05
修稿时间:2003年4月15日

Preparation and Application of Cationic Starch Flocculant Using Microwave Radiation in Dry Process
Wang Chen ,Chen Jierong ,Zong Gang ,Chen Ruifen.Preparation and Application of Cationic Starch Flocculant Using Microwave Radiation in Dry Process[J].Chemical Industry and Engineering Progress,2003,22(11):1217-1221.
Authors:Wang Chen    Chen Jierong  Zong Gang  Chen Ruifen
Affiliation:Wang Chen 1,2,Chen Jierong 1,Zong Gang 2,Chen Ruifen 3
Abstract:The cationic starch flocculant bearing quaternary ammonium groups was synthesized using natural polymeric starch as raw material and 3-chloro-2-hydroxypropyl-trimethyl ammonium chlorate as cationic etherifying agent by microwave Radiation in dry process. The flocculant has good flocculation and bactericidal function. The effects of miscellaneous factors on synthesis were investigated and the optimum conditions were determined from orthogonal test. The result showed that the relative viscosity of product was 3.18 and the degree of cation substitution was 0.31 when the molar ratio of cationic etherifying agent to starch was 0.35, the molar ratio of NaOH to cationic etherifying agent was 1.2, microwave power was 184?W, and the radiation time was 3?min.
Keywords:cationic starch  quatemary ammonium salt  microwave  dry process  flocculant  bactericidal action  
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