| Synthesis and Crystal Structure of a New Glycinato Copper Compound |
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| 作者姓名： | XIANG Sheng-Chang SHENG Tian-Lu FU Rui-Biao HU Sheng-Min WU Xin-Tao ② |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | 中国科学院资助项目;福建省科研项目;中国博士后科学基金;王宽诚教育基金 |
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| 摘 要： | 1 INTRODUCTION Amino acids (AA) are some of the most important biological ligands, and metal ions are known to par- ticipate in a variety of biological reactions, therefore, research on the coordination behavior of metal-ami- no acid complexes is one of the most essential ele- ments of chemical biology1, 2]. For over three deca- des their structures have been of considerable inte- rest and importance in coordination chemistry2, 3]. Studies of these relatively simple complexes may en- ha…
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| 关 键 词： | 合成 晶体结构 铜配合物 氢键 化学分析 |
Synthesis and Crystal Structure of a New Glycinato Copper Compound |
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| XIANG Sheng-Chang,SHENG Tian-Lu,FU Rui-Biao,HU Sheng-Min,WU Xin-Tao.Synthesis and Crystal Structure of a New Glycinato Copper Compound[J].Chinese Journal of Structural Chemistry,2006,25(5):631-635. |
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| Authors: | XIANG Sheng-Chang SHENG Tian-Lu FU Rui-Biao HU Sheng-Min WU Xin-Tao |
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| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | A glycinato copper compound {Cu(NH2CH2COO)(H2O)ClO4} crystallizes in monoclinic, space group P21/n with a = 7.8299(9), b = 10.3807(10), c = 9.4775(12)(A), β = 109.659(6)°, V = 725.43(12)(A)3, Z = 4, Mr = 255.07, Dc = 2.335 g/cm3, F(000) = 508, μ = 3.381 mm-1, R = 0.0270 and wR = 0.0707 for 1677 observed reflections with I > 2σ(I). The title compound contains a chain in the syn-anti conformation, which is generated by the glide-plane operation. The adjacent layers made up of the chains through the connection of perchlorate are related by inversion center ope- ration, which links with each other through the hydrogen bonds. |
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| Keywords: | glycinato copper complex chain hydrogen bonds |
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