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密度和冲击强度对ETPE发射药燃烧特性的影响
引用本文:张邹邹,赵宏立,刘毅,刘来东,靳建伟,张衡,赵瑛.密度和冲击强度对ETPE发射药燃烧特性的影响[J].含能材料,2012,20(2):193-197.
作者姓名:张邹邹  赵宏立  刘毅  刘来东  靳建伟  张衡  赵瑛
作者单位:西安近代化学研究所,陕西 西安,710065
基金项目:国防科技重点实验室基金资助(批准号:9140C3502010902)
摘    要:通过密闭爆发器、高压熄火装置、扫描电子显微镜(SEM)以及发射药理化性能检测技术,研究密度和冲击强度对含能热塑性弹性体(ETPE)发射药燃烧特性的影响。结果表明,BAMO/AMMO基ETPE发射药的实测密度大于理论密度的84%时,密度对燃烧特性影响明显,密度增加,燃烧速度、燃速系数和压力指数降低;冲击强度与燃烧速度和燃速压力指数呈一定负相关性。

关 键 词:应用化学  ETPE发射药  3  3-二叠氮基甲基氧丁环/3-叠氮甲基-3-甲基氧丁环共聚物(BAMO/AMMO)  燃烧特性  密度  冲击强度
收稿时间:2011/3/18 0:00:00
修稿时间:2011/9/13 0:00:00

Effect of Density and Impact Intensity on Combustion Performance of ETPE Gun Propellants
ZHANG Zou-zou,ZHAO Hong-li,LIU yi,LIU Lai-dong,JIN Jian-wei,ZHANG Heng and ZHAO Ying.Effect of Density and Impact Intensity on Combustion Performance of ETPE Gun Propellants[J].Chinese Journal of Energetic Materials,2012,20(2):193-197.
Authors:ZHANG Zou-zou  ZHAO Hong-li  LIU yi  LIU Lai-dong  JIN Jian-wei  ZHANG Heng and ZHAO Ying
Affiliation:(Xi′an Modern Chemistry Research Institute,Xi′an 710065,China)
Abstract:The effects of density and impact intensity on combustion properties of energetic thermoplastic elastomer(ETPE) gun propellants were studied by closed bomb test, high pressure flameout set, scanning electron microscopy (SEM) and physicochemical property test. The results show when the actual density of ETPE gun propellant (BAMO/AMMO based) is 84% more than that of theoretical density, with increase of the density, the burning rate, burning-rate coefficients and pressure exponent of ETPE gun propellants reduce. There is a adverse correlation between the impact intensity and the burning rate and pressure exponent of ETPE gun propellants.
Keywords:applied chemistry  ETPE gun propellant  a copolymer of 3  3-diazidomethyl oxetane and 3-azidomethyl-3-methyl-3-methyl oxetane(BAMO/AMMO)  combustion performance  density  impact intensity
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