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The Purity and Thermal Stability in Air of Metal-Encapsulating Carbon Nanocapsules (MECNCs)
Authors:Motohiro Uo   Hanako Kachi   Tsukasa Akasaka   Fumio Watari   Yoshinori Sato   Kenichi Motomiya   Kazuyuki Tohji
Affiliation: a Department of Biomedical Materials and Engineering, Graduate School of Dentistry, Hokkaido University, Sapporo, Japanb Graduate School of Environmental Studies, Tohoku University, Sendai, Japan
Abstract:Rare earth elements (Y, La, Ce, Nd, Gd and Dy) encapsulated by carbon nanocapsules (CNCs) were synthesized and their purity and air oxidation stability were estimated. The purity was estimated as the rare earth carbide content. Gd- and Dy-encapsulating CNCs had higher than 30 wt% and others 15 to 20 wt%. Encapsulated rare earth carbide was oxidized by heating in air at 400°C or higher. This suggested oxidation damage to the graphene capsules of CNCs.
Keywords:Metal encapsulating carbon nanocapsules  rare earth  carbide  purity  thermal stability
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