| 偶氮苯基及嘧啶环取代丁二炔非线性光学材料的合成及表征 |
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| 引用本文： | 王江洪,余从煊,沈玉全. 偶氮苯基及嘧啶环取代丁二炔非线性光学材料的合成及表征[J]. 北京理工大学学报(英文版), 1996, 5(2): 123-129 |
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| 作者姓名： | 王江洪 余从煊 沈玉全 |
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| 作者单位： | 北京理工大学化工与材料学院，中国科学院感光化学研究所 |
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| 摘 要： | 首次报导了：①５－（２－甲硫基－４－甲基－５－嘧啶基）－２．４－戊二炔－１－醇－４－Ｎ，Ｎ－二甲氨基偶氮苯－４’－磺酸酯（ＰＤＡＢＳ－１）；②５－（２－甲硫基－４－甲基－５－嘧啶基）－２．４－成二炔－１－醇－偶氮苯－４－磺酸酯（ＨＤＡＢＳ－１）；③２．４－已二炔－１－醇－６－醇－４－二甲氨基偶氮苯－４’－磺酸酯（ＰＤＡＢＳ－２）；④２，４－已二炔－１－醇－６－醇－偶氮苯－４－磺酸酯（ＨＤＡＢＳ－２）四种新化合物，它们的结构已由ＩＲ（ＫＢｒ），１Ｈ－ＮＭＲ（ＣＤ３ＣＯ’ＴＭＳ）．ＭＳ、元素分析所证实．制成其中两种化合物的极化聚合取向膜并测试了其非线性光学系数Ｘ（３），ｄ３３，βμ值．
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| 关 键 词： | 偶氮苯；嘧啶；二炔；三阶非线性 |
Synthesis and Characterization of Nonlinear Optical Material of Substituted Diacetylenes with Azophenyl Group and Pyrimidine Ring |
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| Wang Jianghong,Yu Congxuan and Shen Yuquan. Synthesis and Characterization of Nonlinear Optical Material of Substituted Diacetylenes with Azophenyl Group and Pyrimidine Ring[J]. Journal of Beijing Institute of Technology, 1996, 5(2): 123-129 |
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| Authors: | Wang Jianghong Yu Congxuan Shen Yuquan |
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| Affiliation: | School of Chemical Engineering and Materials Science. Beijing Institute of Technology, Beijing 100081;School of Chemical Engineering and Materials Science. Beijing Institute of Technology, Beijing 100081;Institute of Photographic Chemistry. Academia Sinica. Beijing 100101 |
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| Abstract: | ?-(2-methylthio -4 -methyl -5 -pyrimidinyl)-2. 4 - pentadiyn- 1 -ol- (4- N. N-dimethylamino-azobenzene -4' -sulfonate) (PDABS - 1 ). ②5 -(2 -methylthio -4 -methyl -5-pyrimidinyl)- 2.4 -pentadiyn- 1 -ol - (azobenzene - 4 -sulfonate) (PDABS -2 ). ③2. 4 -hexadiyn - 1 -ol-6- (4 - N, N-dimethylamino-azobenzene-4'-sulfonate) (HDABS - 1 ), ④2. 4 -hexadiyn - 1-ol -6 - (azobenzene4-sulfonate) (HDABS-2), the four new compounds are synthesize. The structures of the new compounds have been demonstrdted by elemental analysis. IR(KBr). 1H-NMR (CD3CO/TMS),MS. Their X(3), d33. βμ and the fabrication of their polarization orientated thin film also have ben reported in this paper. |
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| Keywords: | azophenyl pyrimidine diacetylene third order nonlinearity |
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