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热萃取污油的降凝处理研究
引用本文:李俊,江绍静,屈撑囤,秦芳玲.热萃取污油的降凝处理研究[J].西安石油大学学报(自然科学版),2011,26(6):75-78,10,11.
作者姓名:李俊  江绍静  屈撑囤  秦芳玲
作者单位:1. 西安石油大学陕西省环境污染控制技术与储层保护重点实验室,陕西西安,710065
2. 陕西延长石油集团(研究院),陕西西安,710066
基金项目:陕西省"13115"重大科技专项
摘    要:经热萃取从含油污泥中得到的回收污油凝固点高、流动性差,为降低凝点改善其低温流动性,分别采用降凝剂及降凝剂与超声波联合处理的方法,对回收污油进行降凝处理.结果表明:在众多降凝剂中EVA的降凝效果较好,且当反应时间为0.5 h、反应温度为75℃、降凝剂的质量浓度为400 mg/L时,污油凝点从48℃降低到12℃,降凝率达75%;若将降凝剂和超声波联合使用,凝点可降到5℃,降凝率达90%;处理后的污油与原油混合具有良好的输送性能.

关 键 词:污油  降凝剂  超声波  降凝率

Study on pour point decreasing of the polluted oil obtained oily sludge by thermal extraction technology
LI Jun,JIANG Shao-jing,QU Cheng-tun,QIN Fang-ling.Study on pour point decreasing of the polluted oil obtained oily sludge by thermal extraction technology[J].Journal of Xian Shiyou University,2011,26(6):75-78,10,11.
Authors:LI Jun  JIANG Shao-jing  QU Cheng-tun  QIN Fang-ling
Affiliation:LI Jun1,JIANG Shao-jing2,QU Cheng-tun1,QIN Fang-ling1(1.Key Laboratory of Shaanxi Province for Environmental Pollution Control Technology & Oilfield Reservoir Protection,Xi'an Shiyou University,Xi'an 710065,Shaanxi,China,2.Research Institute of Shaanxi Yanchang Petroleum Group,Xi'an 710066,China)
Abstract:The polluted oil is characterized by high pour point and poor flowability.In order to decrease its pour point and improve its flowability at low temperature,the polluted crude oil was treated by different depressants and ultrasonic wave separately,and by the combination of screened depressant with ultrasonic wave.It is shown that,depressant EVA has better pour point decreasing effect than other depressants,and when the reaction time is 0.5 h,temperature is 75 ℃ and its mass concentration is 400 mg/L,the freezing point of the polluted oil can drop from 48 ℃ to 12 ℃ and the pour point decreasing ratio reaches to 75%.Furthermore,the pour point is decreased to 5 ℃ and the pour point decreasing ratio reaches to 90% when the depressant EVA is combined with ultrasonic wave.The mixture of the treated polluted oil and crude oil has excellent transport performance,and it can meet the demand of transport properties of crude oil.
Keywords:polluted oil  depressant  ultrasonic wave  pour point decreasing ratio  
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