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Compositional plane of a wide-gap semiconductor CaCdSeS lattice-matched to InP and GaAs
Authors:S Abe  K Masumoto
Affiliation:

The Research Institute for Electric and Magnetic Materials, 2-1-1 Yagiyama-minami, Sendai 982-0807, Japan

Abstract:We have investigated compositional plane of a wide band gap solid solution semiconductor Ca1?xCdxSe1?ySy (xless-than-or-equals, slant0.32) using powder synthesis under thermal equilibrium condition. The solubility limit at 1273 K varies with respect to the Se concentration y, taking a minimum Cd solubility limit of 0.12 at y=0.8 and a maximum limit of 0.32 at y=1.0. It is found that the system can be lattice-matched to GaAs and InP under covering the energy band gap of ultraviolet–visible region. These results allow to design optoelectronic devices adopting the Ca1?xCdxSe1?ySy system.
Keywords:A1  Solid solutions  B1  Calcium compounds  B2  Semiconducting II–VI materials
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