| 镍系胶体催化丁二烯聚合反应各组分相互作用的研究 |
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| 引用本文： | 魏庆莉,夏少武,王保银,杨泽福. 镍系胶体催化丁二烯聚合反应各组分相互作用的研究[J]. 青岛科技大学学报(自然科学版), 1998, 0(4) |
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| 作者姓名： | 魏庆莉 夏少武 王保银 杨泽福 |
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| 作者单位： | 青岛化工学院应用化学系 |
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| 摘 要： | 已知在加氢汽油介质中Ｎｉ（ｎａｐｈ）２－Ａｌ（ｉ－Ｂｕ）３－（ＢＦ３·ＯＥｔ２＋ｎ－Ｃ８Ｈ１７ＯＨ）体系为胶体催化剂。本工作应用ＦＴ－ＩＲ谱结合Ｔｙｎｄａｌ效应、电导率、ＵＶ－Ｖｉｓ、ＥＳＲ谱对催化剂各组分的相互作用进行研究。得出Ｎｉ（ｎａｐｈ）２被Ａｌ（ｉ－Ｂｕ）３还原的主要产物是Ｎｉ０；被Ａｌ（ｉ－Ｂｕ）２ＯｉＢｕ还原的主要产物是Ｎｉｎａｐｈ。Ｎｉ０聚结成胶粒（Ｎｉ０）ｎ，胶粒表面的Ｎｉ０或吸附的Ｎｉ＋是活性中心组分，与（ｉ－Ｂｕ）２ＡｌＢＦ４形成配合物，给出了活性中心模型。丁二烯具有稳定胶粒的作用。
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| 关 键 词： | 催化剂；胶体催化剂；丁二烯；聚合 |
Reaction Mechanism of Nickel Colloidal Catalyst System Catalyzing Polymerization of Butadiene |
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| Wei Qingli Xia Shaowu Wang Baoyin Yang Zefu. Reaction Mechanism of Nickel Colloidal Catalyst System Catalyzing Polymerization of Butadiene[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 1998, 0(4) |
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| Authors: | Wei Qingli Xia Shaowu Wang Baoyin Yang Zefu |
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| Abstract: | By IR spectrum, Tyndall effect, electric conductivity, UV Vis and ESR spectra were studied the reaction mechanism of catalyst components. The main reduced product of Ni(naoh) 2 by Al(i Bu) 3 was Ni 0; the main reduced product by (i Bui) 2AlOiBu was Ninaph. Ni 0 aggregated as colloidal particles (Ni 0) n,Ni 0 and Ni located on the surface of colloidal particles were active center parts. They coordinated with (i Bu) 2AlBF 4. |
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| Keywords: | catalyst colloidal catalyst butadience polymerization |
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