Anisotropic phase transition of rutile under shock compression

Shock recovery experiments for single crystal and powdered specimens of TiO₂ with the rutile structure were performed in the pressure range up to 72 GPa. Single crystal specimens were shocked parallel to [100], [110] and [001] directions. X-ray powder diffraction analysis showed that the amount of -PbO₂ type TiO₂ produced by shock-loading depended strongly on the shock propagation direction. The maximum yield (about 70%) was observed for shock loading to 36 GPa parallel to the [100] direction. In the [001] shock direction, the yield is much smaller than that of the [100] direction. This anisotropic yield was consistent with the observed anisotropy of the phase transition pressure in shock compression measurements. However, transformation to the -PbO₂ type cannot explain the large volume change observed above about 20 GPa. On the basis of the high pressure behavior of MnF₂, we assumed that the high pressure phase was either fluorite or distorted fluorite type and that the phase conversion to the -PbO₂ type was induced spontaneously in the pressure reduction process.We present a displacive mechanism of phase transition under shock compression from the rutile structure to the fluorite structure, in which the rutile [100] is shown to correspond to the fluorite [001] or [110] and the rutile [001] to the fluorite [110]. Direct evidence is obtained by examining the [100] shocked specimen by high resolution electron microscopy.