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电解质支持型固体氧化物燃料电池的制备及其工作稳定性
引用本文:刘润茹,王德军,冷静.电解质支持型固体氧化物燃料电池的制备及其工作稳定性[J].吉林大学学报(理学版),2014,52(3):587-590.
作者姓名:刘润茹  王德军  冷静
作者单位:1. 长春大学 理学院材料科学与工程实验室, 长春 130022; 2. 长春大学 继续教育学院, 长春 130022;3. 长春工业大学 基础科学学院, 长春 130012
基金项目:吉林省自然科学基金(批准号:201215109);吉林省发改委项目基金(批准号:JF2013C050-1;JF2012C024);吉林省教育厅项目基金(批准号:2013269)
摘    要:利用固相反应法制备固体氧化物燃料电池(SOFC)的复合阳极材料NiO-ScSZ和复合阴极材料(La0.8Sr0.2)0.98MnO3(LSM),并对组装的电解质支持型单电池NiO-ScSZ-LSM进行I-V性能测试,其输出电压每0.2A为0.9V.在外加恒定电流密度(0.2A/cm2)的条件下,利用电化学测试仪测试该电池的总电压为每1 000h衰减0.02V.电流遮断法解析表明,该单电池电压衰减主要为阴极过电压所致.

关 键 词:燃料电池  电流遮断法  阴极过电压  稳定性  
收稿时间:2013-10-27

Preparation and Endurance of Electrolyte SupportedSolid Oxide Fuel Cell
LIU Runru,WANG Dejun,LENG Jing.Preparation and Endurance of Electrolyte SupportedSolid Oxide Fuel Cell[J].Journal of Jilin University: Sci Ed,2014,52(3):587-590.
Authors:LIU Runru  WANG Dejun  LENG Jing
Affiliation:1. Lab of Materials Science and Engineering, College of Science, Changchun University, Changchun 130022, China;[JP]2. College of Continuing Education, Changchun University, Changchun 130022, China;3. School of Basic Sciences, Changchun University of Technology, Changchun 130012, China
Abstract:Cermet anode material NiO ScSZ and cathode material (La0.8Sr0.2)0.98MnO3 (LSM) were prepared via solid state reaction method. The performance electrolyte supported single cell of NiO ScSZ LSM exibited an output voltage of 0.9 V at 0.2 A described by current voltage characte
rized curve. The investigation on the endurance of the single cell indicates that the whole voltage decay is 0.02 V per 1 000 h(at a current density of 0.2
A/cm2)by electro chemical measurement. The main resource of it comes from cathodic over voltage by galvanic current interruption method.
Keywords:fuel cell  galvanic current interruption method  cathodic over voltage  duality
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