| 两个由异烟酰胺构筑的钴、镍配合物的合成及晶体结构 |
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| 引用本文： | 刘 博,李秀梅,周 实,王庆伟,李传碧.两个由异烟酰胺构筑的钴、镍配合物的合成及晶体结构[J].无机化学学报,2012,28(5):1019-1024. |
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| 作者姓名： | 刘 博 李秀梅 周 实 王庆伟 李传碧 |
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| 作者单位： | 1. 吉林师范大学化学学院,吉林师范大学环境友好材料制备与应用省部共建教育部重点实验室,四平 136000
2. 通化师范学院化学系,通化,134002 |
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| 基金项目： | 吉林省教育厅科学技术研究 |
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| 摘 要： | 采用溶液培养法,在室温下合成了2个新的过渡金属配合物Co(inta)2(H2O)4]Co(H2O)6](tdc)2.2H2O(1)和Ni(inta)2(H2O)4](tdc).2H2O(2)(inta=异烟酰胺,H2tdc=2,5-噻吩二甲酸)。并对其进行了元素分析、红外光谱、紫外光谱、热重和X-射线单晶衍射测定。这两个配合物通过氢键和π-π相互作用形成了三维超分子网状结构。
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| 关 键 词： | 晶体结构 钴配合物 镍配合物 |
Synthesis and Crystal Structure of Two Complexes of Cobalt, Nickel Assembled by Isonicotinamide |
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| LIU Bo,LI Xiu-Mei,ZHOU Shi,WANG Qing-Wei and LI Chuan-Bi.Synthesis and Crystal Structure of Two Complexes of Cobalt, Nickel Assembled by Isonicotinamide[J].Chinese Journal of Inorganic Chemistry,2012,28(5):1019-1024. |
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| Authors: | LIU Bo LI Xiu-Mei ZHOU Shi WANG Qing-Wei and LI Chuan-Bi |
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| Affiliation: | Department of Chemistry, Jilin Normal University, Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China,Department of Chemistry, Tonghua Teachers College, Tonghua, Jilin 134002, China,Department of Chemistry, Jilin Normal University, Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China,Department of Chemistry, Jilin Normal University, Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China and Department of Chemistry, Jilin Normal University, Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China |
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| Abstract: | Two transitional metal complex Co(inta)2(H2O)4]Co(H2O)6](tdc)2·2H2O(1) and Ni(inta)2(H2O)4](tdc)·2H2O(2)(inta=isonicotinamide,H2tdc=2,5-thiophenedicarboxylic acid) have been synthesized by employing the solution a preparation method at room temperature.They were structurally characterized by elemental analysis,IR spectrum,UV spectrum,TG and single-crystal X-ray diffraction.They are further extended into a three-dimensional supramolecular network structure through hydrogen bonds and π-π interactions.CCDC:862125,1;862126,2. |
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| Keywords: | crystal structure cobalt complex nickel complex |
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