| 活性炭填充PEG/PVDF杂化膜的脱硫性能 |
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| 引用本文： | 张杏梅,胡文玲,孙鹤翔,韩小龙,王玉琪.活性炭填充PEG/PVDF杂化膜的脱硫性能[J].化工学报,2018,69(2):866-872. |
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| 作者姓名： | 张杏梅 胡文玲 孙鹤翔 韩小龙 王玉琪 |
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| 作者单位： | 1.西安文理学院化学工程学院, 陕西 西安 710065;2.西北大学化工学院, 陕西 西安 710069;3.化学工程联合国家重点实验室, 清华大学化学工程系, 北京 100084 |
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| 基金项目： | 化学工程联合国家重点实验室开放基金项目（SKL-ChE-16A04）；陕西省教育厅专项科研计划项目（16JK1755）；西安市科技计划项目（2017CGWL28）；西北大学研究生自主创新项目（YZZ17135）。 |
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| 摘 要： | 制备了不同活性炭（AC）填充量的AC-PEG/PVDF杂化膜，并对其形貌与结构进行了相应的表征。以噻吩/正庚烷混合物作为模拟汽油体系，研究了所制备AC-PEG杂化膜的渗透汽化脱硫性能。研究表明，填充活性炭后，膜的脱硫性能明显提高。当活性炭填充量为5%，温度为85℃时，与未填充的PEG膜相比，AC-PEG/PVDF杂化膜的渗透通量由0.43 kg·（m2·h）-1提高至1.14 kg·（m2·h）-1，富硫因子由7.29提高至9.47。
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| 关 键 词： | 活性炭 PEG 渗透汽化 脱硫 |
| 收稿时间： | 2017-08-14 |
| 修稿时间： | 2017-12-21 |
Desulfurization performance of activated carbon filled PEG/PVDF hybrid membrane |
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| ZHANG Xingmei,HU Wenling,SUN Hexiang,HAN Xiaolong,WANG Yuqi.Desulfurization performance of activated carbon filled PEG/PVDF hybrid membrane[J].Journal of Chemical Industry and Engineering(China),2018,69(2):866-872. |
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| Authors: | ZHANG Xingmei HU Wenling SUN Hexiang HAN Xiaolong WANG Yuqi |
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| Affiliation: | 1.School of Chemical Engineering, Xi'an University, Xi'an 710065, Shaanxi, China;2.School of Chemical Engineering, Northwest University, Xi'an 710069, Shaanxi, China;3.State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China |
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| Abstract: | Activated carbon filled PEG/VPDF membranes with different activated carbon (AC) loading were prepared. The morphology and structure of the prepared AC-PEG/PVDF hybrid membranes were characterized. The thiophene/n-heptane mixture was used as a simulated gasoline system, the desulfurization of membranes were studied systematically. The results showed that the desulfurization of the AC-PEG/PVDF hybrid membranes were improved. When the content of activated carbon is 5% and the temperature is 85℃, the permeation flux and sulfur enrichment factor of the membrane were improved from 0.43 kg·(m2·h)-1 and 7.29 to 1.14 kg·(m2·h)-1 and 9.47, respectively. |
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| Keywords: | activated carbon PEG pervaporation desulfurization |
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