| 用重氮盐引发N-乙烯咔唑之光聚合研究 |
| |
| 引用本文： | 邱家白,宫鉴非,杜金环.用重氮盐引发N-乙烯咔唑之光聚合研究[J].高分子学报,1989,0(5):616-619. |
| |
| 作者姓名： | 邱家白 宫鉴非 杜金环 |
| |
| 作者单位： | 中国科学院化学研究所 北京
(邱家白，宫鉴非)，中国科学院化学研究所 北京(杜金环) |
| |
| 基金项目： | 北京分子动态结构开放实验室资助项目 |
| |
| 摘 要： | <正> 聚N-乙烯咔唑P(N-VCz)]是典型的有机光导体,已被广泛应用于静电照相和光导热塑全息记录中。 N-乙烯咔唑是一种聚合活性较大的单体,聚合反应可通过自由基、阳离子、Zeigler-Natta型催化剂和电荷转移引发等途径进行。 已有报道,芳香族重氮盐可作为光聚合引发剂。如对环氧化合物、丙烯腈等单体的聚
|
| 关 键 词： | N-乙烯咔唑 光聚合 重氮盐 |
| 收稿时间： | 1987-12-22 |
STUDY ON THE PHOTOPOLYMERIZATION OF N-VINYLCA- RBAZOLE INITIATED BY 4-N,N-DIETHYLAMINOBENZENE DIAZONIUM FLUOROBORATE |
| |
| QIU Jia-bai,GONG Jian-fei,DU Jin-huan.STUDY ON THE PHOTOPOLYMERIZATION OF N-VINYLCA- RBAZOLE INITIATED BY 4-N,N-DIETHYLAMINOBENZENE DIAZONIUM FLUOROBORATE[J].Acta Polymerica Sinica,1989,0(5):616-619. |
| |
| Authors: | QIU Jia-bai GONG Jian-fei DU Jin-huan |
| |
| Affiliation: | Institute of Chemistry; Academia Sinica; Beijing |
| |
| Abstract: | Photopolymerization of N-vinylcarbazole initiated by 4-N,N-diethylaminobenzene diazo-nium fluoroborate has been studied. Based on the solvent and retarder effect as well as spectrum measurement, a cationic initiation mechanism was suggested. |
| |
| Keywords: | N-vinylcarbazole Photopolvmerization Diazonium salt |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
|
点击此处可从《高分子学报》下载全文 |
