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以氧化镁和氧化锌为主稳定剂的PVC的热稳定性和力学性能
引用本文:钟世云,陈玉梅.以氧化镁和氧化锌为主稳定剂的PVC的热稳定性和力学性能[J].中国塑料,2004,18(11):78-80.
作者姓名:钟世云  陈玉梅
作者单位:同济大学材料学院 上海200092 (钟世云),同济大学材料学院 上海200092(陈玉梅)
摘    要:用HAAKE流变仪研究了氧化镁/氧化锌稳定体系对聚氯乙烯的动态热稳定性能。结果发现,在氧化镁/氧化锌质量比为2/3的条件下,配合环氧大豆油、硬脂酸钙、无毒亚磷酸酯和有机稳定剂作为辅助稳定剂,其初期着色和热稳定效果都超过了市售钙锌稳定体系,流变性能和动态热稳定特性接近铅盐稳定体系。用这种稳定体系稳定的PVC的力学性能与市售钙锌稳定体系稳定的相当。

关 键 词:聚氯乙烯  热稳定性  氧化镁  氧化锌  力学性能

Thermal Stability and Mechanical Properties of PVCwith Magnesium Oxide and Zinc Oxide as Main Stabilizers
ZHONG Shi-yun,CHEN Yu-mei.Thermal Stability and Mechanical Properties of PVCwith Magnesium Oxide and Zinc Oxide as Main Stabilizers[J].China Plastics,2004,18(11):78-80.
Authors:ZHONG Shi-yun  CHEN Yu-mei
Abstract:The dynamic thermal stabilizing effect of magnesium oxide/zinc oxide mixture on PVC was studied with HAAKE Rheometer. The results sh owed that when the mass ratio of magnesium oxide/zinc oxide was 2/3, aided w ith EBSO, calcium stearate, phosphite ester and organic stabilizer, a better sta bilizing effect on PVC was exhibited than a commercial calcium/zinc stabilizer, which can be compared with the lead stabilizing system. The mechanical propertie s of PVC containing the new stabilizing system were similar to those using the c ommercial calcium/zinc stabilizers.
Keywords:poly (vinyl chloride)  thermal stability  magnesium o xide  zinc oxide  mechanical property
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