Electropolymerization of hydrogen bond supramolecular associations between terthiophene‐3‐acetic acid and 4,4′‐bipyridine |
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| Authors: | Layla Beouch Sylvie Boileau Claude Chevrot François Tran‐Van |
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| Affiliation: | 1. Université de Cergy‐Pontoise, Neuville‐sur‐Oise, Cergy, France;2. Université Paris Est, Thiais, France;3. Université Fran?ois Rabelais de Tours, Laboratoire de Physico‐Chimie des Matériaux et des Electrolytes pour l'Energie, Tours, France |
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| Abstract: | Supramolecular assemblies based on 4,4′‐bipyridine as hydrogen acceptor and a terthiophene carboxylic acid (3‐TTAA) as hydrogen donor were synthesized and characterized by Fourier transform IR spectroscopy and DSC. Their electropolymerization was successful in methylene chloride or acetonitrile. The concept of using such supramolecular assemblies in electropolymerization opens the way to the facile synthesis of new π‐conjugated polymers. © 2017 Society of Chemical Industry |
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| Keywords: | hydrogen bonding self‐assembly 4 4′ ‐bipyridine terthiophene carboxylic acid electropolymerization |
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