| 反相微乳液中苯酚硝化反应选择性的研究 |
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| 引用本文： | 马松艳,李学杰,褚莹.反相微乳液中苯酚硝化反应选择性的研究[J].分子科学学报,2006,22(4):247-250. |
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| 作者姓名： | 马松艳 李学杰 褚莹 |
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| 作者单位： | 1. 东北师范大学化学学院,吉林,长春,130024;绥化学院化学系,黑龙江,绥化,152061
2. 东北师范大学化学学院,吉林,长春,130024 |
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| 基金项目： | 国家自然科学基金资助项目(20573017) |
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| 摘 要： | 采用气相色谱内标法研究了苯酚在AOT/异辛烷/水、CTAB/正癸醇/异辛烷/水、DBSA/异辛烷/水3种反相微乳液中进行硝化反应的选择性;考察了表面活性剂种类、反应时间、反应温度以及反相微乳液的含水量等因素对反应选择性的影响.研究结果表明,苯酚在微乳液体系中的硝化反应具有明显的邻位选择性,阴离子表面活性剂DB-SA体系的邻位选择性最高,这与它同时具有微乳催化和酸催化作用有关.
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| 关 键 词： | 苯酚硝化 选择性 微乳液 表面活性剂 |
| 文章编号： | 1000-9035(2006)04-0247-04 |
| 收稿时间： | 02 17 2006 12:00AM |
| 修稿时间： | 2006年2月17日 |
Study of the selectivity of phenol nitration reaction in reverse microemulsion |
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| MA Song-yan,LI Xue-jie,CHU Ying.Study of the selectivity of phenol nitration reaction in reverse microemulsion[J].Journal of Molecular Science,2006,22(4):247-250. |
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| Authors: | MA Song-yan LI Xue-jie CHU Ying |
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| Affiliation: | 1. Faculty of Chemistry,Northeast Normal University,Changchun 130024,China;2. Department of Chemistry,Suihua College,Suihua 152061 ,China |
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| Abstract: | The nitration reaction products of phenol in AOT/isooctane/water,CTAB/n-Decyl alcohol/isooctane/water and DBSA/isooctane/water reverse microemulsion systems were investigated by gas chromatography inner mark method;the effect of the surfactant,reaction time,temperature and the water content of reverse microemulsion was also investigated.The results indicated that it has obviously ortho-selectivity of the nitration reaction of phenol in reverse microemulsion system,the selectivity is the highest in the anionic surfactant DBSA system.It is related to the double effect of microemulsion catalyzed and acid catalyzed. |
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| Keywords: | phenol nitration selectivity microemulsion surfactants |
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