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巯基三唑自组装膜修饰金电极对对苯二酚的电催化研究
引用本文:张双圣,杨秋霞,刘汉湖. 巯基三唑自组装膜修饰金电极对对苯二酚的电催化研究[J]. 上海电力学院学报, 2009, 25(6): 575-578
作者姓名:张双圣  杨秋霞  刘汉湖
作者单位:1. 中国矿业大学,环境与测绘学院,江苏,徐州,221116
2. 济南大学,化学化工学院,山东,济南,250022
摘    要:实验采用自组装膜法将巯基三唑修饰在金电极上.结果表明:修饰后的金电极对对苯二酚产生明显的催化作用;扫描速率的平方根与对苯二酚氧化峰电流存在相关关系,表明对苯二酚的氧化还原反应受扩散控制;对苯二酚浓度与其氧化峰电流呈较好的线性关系,可以用来分析和检测该浓度范围内对苯二酚的含量.

关 键 词:巯基三唑  金电极  自组装膜  对苯二酚  催化作用
收稿时间:2009-06-30

Study on the Catalysis of Gold Electrode Self-modified by Mercapto-triazole on the Hydroquinone
ZHANG Shuang-sheng,YANG Qiu-xia and LIU Han-hu. Study on the Catalysis of Gold Electrode Self-modified by Mercapto-triazole on the Hydroquinone[J]. Journal of Shanghai University of Electric Power, 2009, 25(6): 575-578
Authors:ZHANG Shuang-sheng  YANG Qiu-xia  LIU Han-hu
Affiliation:ZHANG Shuang-sheng , YANG Qiu-xia, LIU Han-hu( 1. School of Environment and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, China;2. School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China)
Abstract:Using the gold electrode self-modified by Mercapto-triazole, the experiment produces the result that shows that the gold electrode modified by mercapto-triazole has significant catalysis on the Hydroquinone; there is a correlation between the square root of scan rate and the current of oxidation peak of Hydroquinone, which indicates that the redox reaction is a process controlled by expanding. A good correlation also exists between the concentration of Hydroquinone and its current of oxidation peak, which could be used to analyse and test the concentration of hydroquinone.
Keywords:mercapto-triazole  gold electrode  self-assembled monolayer  hydroquinone  catalysis
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