| 五氧化二氮硝解合成1,4,5,8-四硝基-1,4,5,8-四氮杂双环[4.4.0]癸烷 |
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| 引用本文： | 蔡春,吕春绪. 五氧化二氮硝解合成1,4,5,8-四硝基-1,4,5,8-四氮杂双环[4.4.0]癸烷[J]. 火炸药学报, 2005, 28(2): 50-51 |
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| 作者姓名： | 蔡春 吕春绪 |
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| 作者单位： | 南京理工大学化工学院,江苏,南京,210094;南京理工大学化工学院,江苏,南京,210094 |
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| 摘 要： | 以1，4，5，8-四氮杂双环[4．4．0]癸烷为原料，经亚硝酸钠在盐酸中亚硝化、五氧化二氮在硝硫混酸介质中硝解，得到1，4，5，8-四硝基-1，4，5，8-四氮杂双环[4．4．0]癸烷，并用红外光谱和元素分析方法对产物进行了结构鉴定，产物收率达85％。
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| 关 键 词： | 有机化学 1 4 5 8-四硝基-1 8-四氮杂双环[4.4.0]癸烷 五氧化二氮 硝解 |
| 文章编号： | 1007-7812(2005)02-0050-02 |
| 修稿时间： | 2004-06-04 |
Nitrolysis with Nitrogen Peroxide for Synthesis of 1,4,5,8-Tetranitro-1, 4,5,8-tetraazabicyclo[4.4.0]decalin |
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| CAI Chun,Lü Chun-xu. Nitrolysis with Nitrogen Peroxide for Synthesis of 1,4,5,8-Tetranitro-1, 4,5,8-tetraazabicyclo[4.4.0]decalin[J]. Chinese Journal of Explosives & Propellants, 2005, 28(2): 50-51 |
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| Authors: | CAI Chun Lü Chun-xu |
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| Abstract: | 1,4,5,8-Tetranitro-1,4,5,8-tetraazabicyclo[4.4.0]decalin (TNAD) is used as an explosive and has several superior physical properties, such as heat-resistance and insensitivity to impact. This compound could be prepared from the raw material 1,4,5,8-tetraazabicyclo [4.4.0]decalin via nitrosation with sodium nitrite in hydrochloric acid, and followed nitrolysis with N_2O_5in mixed acid. In nitrolysis step, the effect of reaction medium and the reaction temperature on the yield have been investigated . The structure of compound was characterized by IR and elemental analysis.The total yield could reach as high as 85%. |
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| Keywords: | organic chemisty 1 4 5 8-tetranitro-1 4 5 8-tetraazadecalin nitrogen peroxide nitrolysis |
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