| Abstract: | A hydroxy‐terminated polybutadiene (HTPB)/isophorone diisocyanate (IPDI) elastomer is commonly used as propellant binder material. The thermal degradation of the binder is believed to be an important parameter governing the performance of the propellant. The aging of these binders can be monitored by mechanical property measurements, such as modulus or tensile elongation. These techniques, however, are not easily adapted to binder agents that are dispersed throughout a propellant. In this paper we investigated solid‐state nuclear magnetic resonance (NMR) relaxation times as a means to predict the mechanical properties of the binder as a function of aging time. Proton (1H) spin–lattice and spin–spin relaxation times were insensitive to the degree of thermal degradation of the elastomer. Apparently, these relaxation times depend on localized motions that are only weakly correlated with mechanical properties. A strong correlation was found between the 13C cross‐polarization (CP) NMR time constant, Tcp, and the tensile elongation at break of the elastomer as a function of aging time. A ramped‐amplitude CP experiment was less sensitive to imperfections in setting critical instrumental parameters for this mobile material. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 453–459, 2001 |
