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浅谈缩聚和逐步聚合的教学与学习
引用本文:马松梅,陈厚,李桂英. 浅谈缩聚和逐步聚合的教学与学习[J]. 广州化工, 2011, 39(1): 149-150,155
作者姓名:马松梅  陈厚  李桂英
作者单位:鲁东大学化学与材料科学学院,山东,烟台,264025
摘    要:缩聚和逐步聚合反应是高分子化学教学和学习中的重要内容。本文讨论了缩聚和逐步聚合的关系;线型缩聚反应动力学和线型缩聚缩聚物数均聚合度的计算。线型缩聚反应动力学表达式的推导过程有助于学生初步掌握聚合动力学的一般处理方法;控制线型缩聚物聚合度的手段可以分为三种,通过对这三种情况下线型缩聚聚合度表达式的推导,使学生进一步明确聚合机理及控制聚合度的方法。

关 键 词:缩聚  逐步聚合  聚合动力学  平均聚合度

Teaching and Learning of Polycondensation and Stepwise Polymerization
MA Song-mei,CHEN Hou,LI Gui-ying. Teaching and Learning of Polycondensation and Stepwise Polymerization[J]. GuangZhou Chemical Industry and Technology, 2011, 39(1): 149-150,155
Authors:MA Song-mei  CHEN Hou  LI Gui-ying
Affiliation:MA Song-mei,CHEN Hou,LI Gui-ying(School of Chemistry and Materials Science,Ludong University,Shandong Yantai 264025,China)
Abstract:Polycondensation and stepwise polymerization were very important in the teaching and study of polymerization chemistry.The relationship between polycondensation and stepwise polymerization,polycondensation kinetics and average degree of polycondensate were discussed,and students would be guided to know how to deal with polymeric kinetics by the derivation of the expression of the polymerization reaction rate.There were three means to control the degree of polycondensate,which would be helpful for students t...
Keywords:polycondensation  stepwise polymerization  polymerization kinetics  average degree of polymer  
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