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臭氧消毒中溴酸盐的形成、检测与控制
引用本文:吴清平,孟凡亚,张菊梅,郭伟鹏.臭氧消毒中溴酸盐的形成、检测与控制[J].中国给水排水,2006,22(16):12-15.
作者姓名:吴清平  孟凡亚  张菊梅  郭伟鹏
作者单位:1. 广东省微生物研究所,广东省菌种保藏与应用重点实验室,广东,广州,510070
2. 广东省微生物研究所,广东省菌种保藏与应用重点实验室,广东,广州,510070;中国科学院,南海海洋研究所,广东,广州,510301
摘    要:用臭氧对含溴化物的饮用水进行消毒时会生成溴酸盐副产物,溴酸盐被国际癌症研究机构定为2B级(具有较高的致癌可能性)潜在致癌物。臭氧氧化溴化物生成溴酸盐要经过多步反应,控制溴酸盐生成的方法有加氨、降低pH值、投加活性炭、投加高锰酸盐和增加臭氧投加点的数量等。用臭氧消毒的最终目的是杀灭致病菌,因此如何找到臭氧、致病菌、溴酸盐消毒副产物之间的最佳平衡点还有待进一步研究。

关 键 词:饮用水  溴酸盐  臭氧  离子色谱
文章编号:1000-4602(2006)16-0012-04
收稿时间:2006-01-12
修稿时间:2006-01-12

Formation, Detection and Control of Bromate in the Ozone Disinfection of Drinking Water
WU Qing-ping,MENG Fan-ya,ZHANG Ju-mei,GUO Wei-peng.Formation, Detection and Control of Bromate in the Ozone Disinfection of Drinking Water[J].China Water & Wastewater,2006,22(16):12-15.
Authors:WU Qing-ping  MENG Fan-ya  ZHANG Ju-mei  GUO Wei-peng
Affiliation:1. Guangdong Provincial Key Laboratory of Microbial Collection and Application, Guangdong Institute of Microbiology, Guangzhou 510070, China; 2. South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510301, China
Abstract:Ozonation of drinking water containing bromide may lead to the formation of bromate, which is considered to be a potential 2B-level carcinogen by International Agency for Research on Cancer (IARC). Bromate is formed through multiple reactions during ozonation of drinking water containing bromide. Methods of control the formation of bromate include ammonia addition, pH decreasing, dosing activated carbon or permanganate, and increasing the number of dosing position, etc. The critical objective of ozone disinfection is inactivation of pathogenic bacteria. Therefore, further investigation to find the optimal balance among ozone, pathogenic bacteria and bromate should be conducted.
Keywords:drinking water  bromate  ozone  ion chromatography
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