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Directional solidification and microstructures of near-eutectic Cr–Cr3Si alloys
Authors:H Bei  E P George  E A Kenik  G M Pharr  
Affiliation:

a Department of Materials Science and Engineering, 434 Doughgherty Hall, The University of Tennessee, Knoxville, TN 37996-2200, USA

b Metals and Ceramics Division, Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831-6093, USA

Abstract:Near-eutectic Cr–Cr3Si alloys were directionally solidified in a high-temperature optical floating zone furnace. At the eutectic composition, uniform and well-aligned lamellar structures were obtained over a fairly wide range of solidification conditions, but not at very low or very high growth rates where degenerate and cellular structures, respectively, were obtained. The lamellar spacing was found to increase with decreasing solidification rate, in agreement with the Jackson–Hunt theory. In addition, for a fixed growth rate, the lamellar spacing was found to increase with increasing rotation rate. The growth directions in the lamellar eutectic are found to be left angle bracket1 0 0right-pointing angle bracket for the Cr3Si phase and left angle bracket1 1 1right-pointing angle bracket for the Cr solid-solution phase. Eutectic microstructures (rod or lamellar) could also be produced at off-eutectic compositions, but only for a limited range of growth conditions.
Keywords:Author Keywords: Transition metal silicide  Directional solidification  Eutectic solidification  Microstructure  In situ composite
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