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| ——>——>双核钴簇合物(C6H5CO2CH2C)2Co2(CO)6的合成与结构 | |
| 引用本文： | 游效曾,孟庆金,杨星水,孙守恒,步修仁,黄锦顺.——>——>双核钴簇合物(C6H5CO2CH2C)2Co2(CO)6的合成与结构[J].物理化学学报,1988,4(4):428-431. |
| 作者姓名： | 游效曾 孟庆金 杨星水 孙守恒 步修仁 黄锦顺 |
| 作者单位： | Coordination Chemistry Institute; Nanjing University;Fujian Institute of Research on the Structure of Matter; Academia Sinica |
| 摘 要： | |
| 收稿时间： | 1987-01-07 |
| 修稿时间： | 1987-07-16 |
SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C6H5CO2CH2C)2Co2(CO)6 |
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| You Xiaozeng,Meng Qingjin,Yang Xinshui,Sun Shouheng,Bu Xiuren, Huang Jinshun.SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C6H5CO2CH2C)2Co2(CO)6[J].Acta Physico-Chimica Sinica,1988,4(4):428-431. |
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| Authors: | You Xiaozeng Meng Qingjin Yang Xinshui Sun Shouheng Bu Xiuren Huang Jinshun |
| Affiliation: | Coordination Chemistry Institute; Nanjing University;Fujian Institute of Research on the Structure of Matter; Academia Sinica |
| Abstract: | The cluster (C_6H_5CO_2CH_2C)_2Co_2(CO)_6 has been synthesized and characterized by element analysis, IR, ~1H NMR etc. Its crystal structure has been determined by X-ray diffraction analysis with R=0.060. The crystal is triclinic, space group P_1 with a=0.8933(3) nm, b=1.1830(6) nm, c=1.3199(3) nm, α=65.64(3)°, β=84.55(3)°, γ=72.03(4)°, z=2, D_x=1.584 g cm~(-1) The C≡C and Co-Co form a tetrahedron with appoximate C_(2V) symmetry. The Co-Co bond is metl singal bond. The hybrid state of carbon atoms in the acetylene is between sp and sp~2. |
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