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The effect of the amine structure on photoinitiated free radical polymerization of methyl methacrylate using bisketocoumarin dye
Authors:Demet Karaca Balta  Feyza Karasu  Meral Ayd&#x;n  Nergis Arsu
Affiliation:

aYildiz Technical University, Department of Chemistry, 34210 Davutpaşa, Istanbul, Turkey

Abstract:Photoinitiation of the polymerization of methyl methacrylate by the bis-diethylaminocoumarin dye (BKC) in the presence of various amines was studied in order to determine the efficient amine that leads to the formation of the initiating radicals. RT-FTIR studies were also performed for multifunctional methacrylate. According to photoinduced polymerization and RT-FIR studies, N-methyldiethanol amine was the more efficient H-donor compared with the others.
Keywords:Photoinitiator  Bisketocoumarin  Amine  Polymerization  RT-FTIR
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