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| Hydrothermal Synthesis and Characterization of a Novel Two-dimensional Framework Materials Constructed from Polyoxometalate and Coordination Groups: [H_2Mo_(5.5)V_(10.5)O_(40)(PO_4)][Cu(en)_2]_4·7H_2O | |
| 作者姓名： | CUI Xiao-bing ZHENG Shou-tian SUN Yan-qiong and YANG Guo-yu ** . Coordination and Hydrothermal Chemistry Group State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P. R. China . State Key Laboratory of Coordination Chemistry Najing University Nanjing P. R. China |
| 作者单位： | CUI Xiao-bing 1，ZHENG Shou-tian 1，SUN Yan-qiong 1 and YANG Guo-yu 1，2** 1. Coordination and Hydrothermal Chemistry Group，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002，P. R. China; 2. State Key Laboratory of Coordination Chemistry，Najing University，Nanjing 210093，P. R. China |
| 基金项目： | SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 2 710 5 0and 2 0 1710 4 5 ) ,theMinistryofFinanceofChinaandtheTalentsProgramofChineseAcademyofSciences |
| 摘 要： | IntroductionPolyoxometalatesarewidelystudiedfortheirin terestingapplicationsincatalysis ,electronicconduc tivity ,magnetism ,nonlinearopticsandmedicine1— 4 ] .Whilethemechanismofthesynthesisofpolyoxometalatesremainselusiveandisoftende scribedasself assembly ,thereseemstobeanincreas inguseofthecombinationofthehydrothermalmethodandthestructure directingtemplate .There searchwiththismethodhasdemonstratedthatanum beroftransitionmetaloxides ,typicallyreducedmolybdenumoxides ,mixedvalancevanadiumo… |
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