An Easy Route to Synthesize Novel Mesostructured Silicas Al/SBA-16 and Its Catalytic Application |
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Authors: | Jing Ma Liangsheng Qiang Jinfu Wang Dongyan Tang Xiangbo Tang |
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Affiliation: | (1) Department of Chemistry, Harbin Institute of Technology, Harbin, 150001, China; |
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Abstract: | Abstract Al-containing SBA-16 (with different Si/Al molar ratios) was prepared by an easy post-grafting method using F127 as structure-directing
agent and aluminum isopropoxide as Al source. The structure of the solid catalyst was fully characterized by X-ray diffraction
(XRD) analysis, N2 adsorption, scanning electron micrographs (SEM), transmission electron micrographs (TEM) and 27Al MAS NMR. The results indicated that the materials possess three-dimension caged-like mesostructure and Al was successfully
incorporated into the SBA-16 framework. The acid properties have been estimated by FT-IR of pyridine adsorption (Py-IR). Among
various Si/Al ratios, Al/SBA-16 with Si/Al ratio 20 performed good catalytic activity for the tert-butylation of phenol. Compared to hexagonal mesoporous Al/SBA-15, Al/SBA-16 showed higher catalytic properties due to its
cage-like mesostructure, which could make the active acid sites more accessible to the reactant. |
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