| 一维链状锰配位聚合物[Mn(3,5-Me2PhCO2)2(phen)]n的合成与晶体结构 |
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| 引用本文： | 张春华,李昶红,邝代治,陈满生,李薇,杨颖群,匡云飞. 一维链状锰配位聚合物[Mn(3,5-Me2PhCO2)2(phen)]n的合成与晶体结构[J]. 无机化学学报, 2007, 23(7): 1255-1258 |
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| 作者姓名： | 张春华 李昶红 邝代治 陈满生 李薇 杨颖群 匡云飞 |
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| 作者单位： | 1. 衡阳师范学院化学与材料科学系,衡阳,421008
2. 湖南工学院化学化工系,衡阳,421008 |
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| 基金项目： | 湖南省自然科学基金;湖南省高校重点建设学科资助项目 |
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| 摘 要： | A manganese coordination polymer [Mn(3,5-Me2PhCO2)2(phen)]n(phen=1,10-phenanthroline) has been synthesized by hydrothermal methods. The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1 with a=0.770 3(4) nm, b=1.145 2(6) nm, c=1.537 0(9) nm, α=78.182(9)°, β=77.170(9)°, γ=89.784(9)°, V=1.292 8(12) nm3, Z=2, Mr=533.47, Dc=1.370 g·cm-3, μ=0.549 mm-1, F(000)=554, Rint=0.043 4, R=0.060 8 ,wR=0.148 4. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from phen and four oxygen atoms from four 3,5-dimethylbenzolate molecules, completing an octahedral geometry. And the title complex forms one-dimensional chain structure through bridging 3,5-dimethylbenzolate molecules. CCDC: 642920.
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| 关 键 词： | 锰配位聚合物； 水热法； 晶体结构 |
| 文章编号： | 1001-4861（2007）07-1255-04 |
| 修稿时间： | 2007-01-292007-04-19 |
Synthesis and Crystal Structure of a 1D Manganese Coordination Polymer Constructed by 3,5-dimethylbenzoic Acid with 1,10-phenanthroline |
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| ZHANG Chun-Hu,Li Chang-Hong,KUANG Dai-Zhi,CHEN Man-Sheng,LI Wei,YANG Yin-Qun and KUANG Yun-Fei. Synthesis and Crystal Structure of a 1D Manganese Coordination Polymer Constructed by 3,5-dimethylbenzoic Acid with 1,10-phenanthroline[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(7): 1255-1258 |
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| Authors: | ZHANG Chun-Hu Li Chang-Hong KUANG Dai-Zhi CHEN Man-Sheng LI Wei YANG Yin-Qun KUANG Yun-Fei |
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| Affiliation: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang Hunan 421008,Department of Chemical Engineering, Hunan Institute of Technology, Hengyang Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang Hunan 421008 and Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang Hunan 421008 |
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| Abstract: | A manganese coordination polymer [Mn (3,5-Me2PhCO2)2 (phen)]n (phen =1,10-phenanthroline) has been synthesized by hydrothermal methods. The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P(1) with a=0.770 3 (4) nm, b =1.145 2(6) nm, c =1.537 0(9) nm, α=78.182(9)°,β=0.043 4, R=0.060 8 ,wR=0.148 4. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from phen and four oxygen atoms from four 3,5-dimethylbenzolate molecules, completing an octahedral geometry. And the title complex forms one-dimensional chain structure through bridging 3,5-dimethylbenzolate molecules. CCDC: 642920. |
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| Keywords: | manganese coordination polymer hydrothermal synthesis crystal structure |
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