| 六苯甲酰基六氮杂异伍兹烷的硝解 |
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| 引用本文： | 陈树森,邱文革,于永忠.六苯甲酰基六氮杂异伍兹烷的硝解[J].兵工学报,2000,21(2):116. |
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| 作者姓名： | 陈树森 邱文革 于永忠 |
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| 作者单位： | 北京理工大学,北京,100081 |
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| 摘 要： | 为探索六硝基六氮杂异伍兹烷制备的新方法 ,研究了六苯甲酰基六氮杂异伍兹烷在多种条件下的硝解反应。采用未见文献报道的稀硝酸 /硝酸盐为硝解剂 ,首次实现了苯甲酰胺的硝解 ,以六苯甲酰基六氮杂异伍兹烷为底物 ,得到四硝基二苯甲酰基六氮杂异伍兹烷 ,得率不低于 60 %
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| 关 键 词： | 六硝基六氮杂异伍兹烷 硝解 六苯甲酰基六氮杂异伍兹烷 四硝基二苯甲酰基六氮杂异伍兹烷 |
NITROLYSIS OF HEXABENZOYLHEXAAZAISOWURZITANE |
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| Chen Shusen,Qiu Wenge,Yu Yongzhong.NITROLYSIS OF HEXABENZOYLHEXAAZAISOWURZITANE[J].Acta Armamentarii,2000,21(2):116. |
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| Authors: | Chen Shusen Qiu Wenge Yu Yongzhong |
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| Abstract: | In this paper are summarized studies on the nitrolysis of hexabenzoylhexaazaisowurtzi tane in several nitration conditions with a purpose to find out a new route in synthesizing hexanitrohexaazaisowurtzitane. Nitrolysis of hexabenzoylhexaazaisowurzitane in the system of dilute nitric acid and nitrates gives tetranitrodibenzoylhexaazaisowurzitane with a yield of more than 60%. The nitrolysis of benzoylamide derivatives is first reported. |
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| Keywords: | hexanitrohexaazaisowurzitane nitrolysis hexabenzoylhexaazaisowurzitane tetranitrodibenzoylhexaazaisowurzitane |
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