| 熔融插层法制备聚乳酸/有机蒙脱土纳米复合材料及其性能研究 |
| |
| 引用本文： | 袁龙飞;甄卫军;刘月娥;庞桂林;宋晓玲;黄东;贺盛喜. 熔融插层法制备聚乳酸/有机蒙脱土纳米复合材料及其性能研究[J]. 中国塑料, 2009, 23(7): 34-38. DOI: 10.19491/j.issn.1001-9278.2009.07.008 |
| |
| 作者姓名： | 袁龙飞 甄卫军 刘月娥 庞桂林 宋晓玲 黄东 贺盛喜 |
| |
| 作者单位： | 新疆大学化学化工学院新疆大学化学化工学院新疆大学化学化工学院新疆大学化学化工学院石河子中发化工有限公司石河子中发化工有限公司石河子中发化工有限公司 |
| |
| 摘 要： | 以新疆地产蒙脱土和聚乳酸为原料，通过熔融插层的方法制备了聚乳酸(PLA)/有机蒙脱土（OMMT）纳米复合材料。分别采用X射线衍射仪、扫描电子显微镜、透射电子显微镜、热重分析仪等对复合材料的微观结构、形貌及热稳定性进行了表征和分析。研究表明，PLA大分子链已经插入OMMT片层间，层间距明显增大，形成PLA/OMMT纳米复合材料，体系的相容性良好。PLA/OMMT纳米复合材料的热失重曲线移向高温端，其热分解温度提高。PLA/OMMT纳米复合材料的熔点、维卡软化点、冲击强度、拉伸强度、热稳定性均比PLA基体有明显的提高。PLA/OMMT纳米复合材料的降解性初步研究表明其是一种良好的生物可降解环保塑料。
|
| 关 键 词： | 熔融插层 聚乳酸 结构 性能 有机蒙脱土 纳米复合材料 |
| 收稿时间： | 2009-03-30 |
Properties of PLA/OMMT Nanocomposites Prepared by Melting Intercalation |
| |
| YUAN Long-feiZHEN Wei-junLIU Yue-ePANG Gui-linSONG Xiao-lingHUANG DongHE Sheng-xi. Properties of PLA/OMMT Nanocomposites Prepared by Melting Intercalation[J]. China Plastics, 2009, 23(7): 34-38. DOI: 10.19491/j.issn.1001-9278.2009.07.008 |
| |
| Authors: | YUAN Long-feiZHEN Wei-junLIU Yue-ePANG Gui-linSONG Xiao-lingHUANG DongHE Sheng-xi |
| |
| Abstract: | Polylactic acid /organomontmorillonite (PLA/OMMT) nanocomposites were prepared via melt blending/intercalation. The microstructure, morphology, and thermal properties of PLA/OMMT nanocomposites were characterized by XRD, SEM, TEM, and TGA-DTG.. The layer spacing of OMMT was found obviously increased as a result of intercalation. The TGA-DTG curves of PLA/OMMT nanocomposites were shifted to higher temperature, which illustrated that the enhanced thermal stability. Thermal and mechanical property tests showed that the melting point, Vicat softening point, impact strength, and tensile strength of PLA/OMMT nanocomposites were evidently enhanced compared with neat PLA. The PLA/OMMT nanocomposites also showed an excellent biodegradable behavior. |
| |
| Keywords: | melting intercalation polylactic acid structure property organomontmorillonite nanocomposite |
|
| 点击此处可从《中国塑料》浏览原始摘要信息 |
|
点击此处可从《中国塑料》下载全文 |
