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纳米低温保护剂水合及玻璃化性质的DSC研究
引用本文:徐海峰,刘宝林,郝保同,周国燕.纳米低温保护剂水合及玻璃化性质的DSC研究[J].低温物理学报,2011(6):458-462.
作者姓名:徐海峰  刘宝林  郝保同  周国燕
作者单位:上海理工大学生物系统热科学研究所;
基金项目:国家自然科学基金(批准号:50776060); 教育部新世纪优秀人才计划(批准号:07-0559); 上海市东方学者计划(批准号:S30503)资助的课题~~
摘    要:利用差示扫描量热仪(DSC)研究了羟基磷灰石(HA)纳米微粒对丙三醇溶液冻结过程中水合性质及玻璃化性质的影响.实验结果表明在中高浓度HA纳米颗粒对溶液水合性质影响显著.与未加纳米颗粒的溶液相比,溶液结晶量减少,未冻水含量增大.在较低浓度溶液中,加入纳米颗粒后玻璃化温度变化不明显,但反玻璃化温度明显升高;当溶液浓度达到6...

关 键 词:纳米颗粒  水合性质  结晶量  玻璃化  反玻璃化  DSC

HYDRATION AND VITRIFICATION PROPERTIES OF Nano-CRYOPROTECTANT SOLUTIONS EXAMINED WITH DSC
XU Hai-feng LIU Bao-lin HAO Bao-tong ZHOU Guo-yan Institute of Biothermal Science,University of Shanghai for Science , technology,shanghai.HYDRATION AND VITRIFICATION PROPERTIES OF Nano-CRYOPROTECTANT SOLUTIONS EXAMINED WITH DSC[J].Chinese Journal of Low Temperature Physics,2011(6):458-462.
Authors:XU Hai-feng LIU Bao-lin HAO Bao-tong ZHOU Guo-yan Institute of Biothermal Science  University of Shanghai for Science  technology  shanghai
Affiliation:XU Hai-feng LIU Bao-lin HAO Bao-tong ZHOU Guo-yan Institute of Biothermal Science,University of Shanghai for Science and technology,shanghai 200093
Abstract:In order to investigate the effects of nanoparticles(HA) on the vitrification properties of cryprotectant solutions at cryogenic temperatures,the hydration properties,vitrification and devitrification of Glycerol aqueous solutions with different sizes and concentrations of HA nanoparticles were employed by differential scanning calorimeter(DSC).Experimental results indicate that the hydration behaviors can be significantly affected by nanoparticles.Compared with other solutions without nanoparticles the cry...
Keywords:Nanoparticles  Hydration  Crystallization quantity  Vitrification  Devitrification  DSC  
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