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聚丁二酸丁二醇酯-聚乳酸共混体系的毛细管流变行为
引用本文:罗发亮,张秀芹,甘志华,季君辉,王笃金.聚丁二酸丁二醇酯-聚乳酸共混体系的毛细管流变行为[J].宁夏工程技术,2010,9(3):233-237.
作者姓名:罗发亮  张秀芹  甘志华  季君辉  王笃金
作者单位:1. 宁夏大学,能源化工重点实验室,宁夏,银川,750021;中国科学院化学研究所,工程塑料院重点实验室,北京,100190
2. 中国科学院化学研究所,工程塑料院重点实验室,北京,100190
3. 中国科学院,理化技术研究所,北京,100080
基金项目:国家自然科学基金资助项目 
摘    要:将聚丁二酸丁二醇酯(PBS)与聚乳酸(PLA)熔融共混,制备共混物PBS-PLA以改性PBS的力学与加工性能,并研究了PBS、PLA及PBS-PLA的流变性能.结果表明,PBS-PLA体系表观黏度随PLA质量分数的增加而增大;剪切敏感性随PLA质量分数的增加而增大;温度敏感性介于PBS和PLA的之间;黏流活化能随PLA质量分数的变化呈现复杂的变化.

关 键 词:聚丁二酸丁二醇酯(PBS)  聚乳酸(PLA)  流变行为

Rheological Properties of Poly butylene succinate and Poly lactic acid blends
LUO Falianga,ZHANG Xiuqin,GAN Zhihua,JI Junhui,WANG Dujin.Rheological Properties of Poly butylene succinate and Poly lactic acid blends[J].Ningxia Engineering Technology,2010,9(3):233-237.
Authors:LUO Falianga  ZHANG Xiuqin  GAN Zhihua  JI Junhui  WANG Dujin
Affiliation:1.Key Laboratory of Energy & Resource in Ningxia,Ningxia University,Yinchuan 750021,China;2.Beijing National Laboratoryfor Molecular Sciences,CAS Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China;3.Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190,China)
Abstract:Poly butylenes succinate(PBS) and Poly lactic acid(PLA) blends was obtained by melt blending for modifying the mechanical and processing performance of PBS.The rheological properties of PBS,PLA and PBS/PLA blends were researched.It was found that the apparent viscosity increases with the increasing of PLA content.The shear sensitive of the blends PBS/PLA increases with the increasing of the PLA conten,and its temperature sensitivity is in the middle of PBS and PLA.Viscous flow activation energy for the PBS/PLA shows complex variation with the different PLA content.
Keywords:Poly butylene succinate(PBS)  Poly lactic acid(PLA)  rheology action
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