| Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2的合成和晶体结构 |
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| 引用本文： | 刘树堂,刘启旺,吴秉芳,索全伶,胡襄,王博义. Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2的合成和晶体结构[J]. 物理化学学报, 1990, 6(6): 730-734. DOI: 10.3866/PKU.WHXB19900618 |
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| 作者姓名： | 刘树堂 刘启旺 吴秉芳 索全伶 胡襄 王博义 |
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| 作者单位： | Department of Chemistry; Nei Monggu University; Hohhot Center of Analysis and Measurement; Fudan University |
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| 摘 要： |
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| 关 键 词： | 铁硫羰簇合物 合成 晶体结构 |
| 收稿时间： | 1989-05-31 |
| 修稿时间： | 1989-12-01 |
SYNTHESIS AND CRYSTAL STRUCTURE OF Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2 |
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| Liu Shu-Tang,Liu Qi-Wang,Wu Bin-Fang,Suo Quan-Ling,Hu Xiang,Wang Be-Yi. SYNTHESIS AND CRYSTAL STRUCTURE OF Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2[J]. Acta Physico-Chimica Sinica, 1990, 6(6): 730-734. DOI: 10.3866/PKU.WHXB19900618 |
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| Authors: | Liu Shu-Tang Liu Qi-Wang Wu Bin-Fang Suo Quan-Ling Hu Xiang Wang Be-Yi |
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| Affiliation: | Department of Chemistry; Nei Monggu University; Hohhot Center of Analysis and Measurement; Fudan University |
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| Abstract: | The title compound Fe_3(CO)_8 (P(SC_6H_5) Cl_2) (μ_3′-S)_2 was synthesised by reacting Fe_3(CO)_9 (μ_3-S)_2 with P (SC_6H_5) Cl_2. The crystal and molecular structure of the title compound has been determined by single crystal diffraction method. Crystal data: triclinic, space group P1, with a=0.7571(1), b=0.9097(1), c=1.7706(2) nm, α=95.03(1), β=101.79(1), γ=105.73(1)°, V =1.1359 nm, Z=2, Dc=1.935 g·cm~(-3). The structure was solved by direct method and difference Fourier synthesis, and refined by full-matrix least-squares with anisotropic thermal paramaters for non-hydrogen atoms, using 3724 observed reflections withI≥3σ(I). The final residual factor R=0.025, R_W=0.028.Fe_(CO)_8(P(SC_6H_5)Cl_2)(μ_3-s)_2 has a face-bridged 4e donors and the monosubstituted ligand is on the apical Fe atom. |
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