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Investigation of the mechanism of upconversion luminescence in Er3+/Yb3+ co-doped Bi2Ti2O7 inverse opal
引用本文:严冬,杨正文,廖佳燕,吴航俊,邱建备,宋志国,周大成,杨勇,尹兆益.Investigation of the mechanism of upconversion luminescence in Er3+/Yb3+ co-doped Bi2Ti2O7 inverse opal[J].Chinese Optics Letters,2013(4):60-63.
作者姓名:严冬  杨正文  廖佳燕  吴航俊  邱建备  宋志国  周大成  杨勇  尹兆益
作者单位:Key Laboratory of Advanced Materials in Rare and Precious and Non-ferrous Metals, Ministry of Education, Key Laboratory of Advanced Materials of Yunnan Province, College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
基金项目:supported by the National Natural Science Foundation of China(No.61205181);Zhejiang Provincial Natural Science Foundation of China(No.LQ12E02003);the Natural Science Foundation of Ningbo City(No.2012A610122);the Scientific Research Fund of Zhejiang Provincial Education Department(No.Y201120457);K.C.Wong Magna Fund in Ningbo University
摘    要:Bismuth (Bi)-doped materials have attracted a great deal of attention because of their broadband nearinfrared (near-IR) emission around the wavelength utilized in telecommunications. In this study, broad near-IR emission band from 1 100 to 1 650 nm is generated in the Bi-doped 90GeS2-10Ga2S3 glass and glass-ceramics under 820 nm of light excitation. Based on the analysis of the absorption and emission spectra, the origin of this broadband emission is ascribed to the Bi2-2 dimers. The precipitation of β-GeS2 nanocrystals drastically enhances the emission intensity and lifetime of Bi-doped chalcogenide glass.

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