| 丙烯腈嵌段共聚物的合成及其自组装研究进展 |
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| 引用本文： | 王晓露,马晓燕,宋春莹,王颖.丙烯腈嵌段共聚物的合成及其自组装研究进展[J].中国胶粘剂,2011,20(3). |
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| 作者姓名： | 王晓露 马晓燕 宋春莹 王颖 |
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| 作者单位： | 1. 西北工业大学理学院应用化学系,陕西,西安,710129
2. 山东警察学院,山东,济南,250014 |
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| 基金项目： | 陕西省自然科学基金重点项目 |
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| 摘 要： | 综述了含聚丙烯腈(PAN)嵌段共聚物的合成方法及其在溶液中的自组装技术。对常用的活性自由基聚合方法,如原子转移自由基聚合(ATRP)、可逆加成断裂链转移(RAFT)聚合、氮氧自由基聚合(NMP)以及钴调介自由基聚合(CMRP)等方面的研究进行了总结,同时对PAN类嵌段共聚物在溶液中的自组装技术进行了概括。最后提出了现有技术存在的问题,并对其今后发展方向进行了展望。
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| 关 键 词： | 丙烯腈 嵌段共聚物 自由基聚合 自组装 |
Research progresss of synthesis and self-assembly for acrylonitrile block copolymers |
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| WANG Xiao-lu,MA Xiao-yan,SONG Chun-ying,WANG Ying.Research progresss of synthesis and self-assembly for acrylonitrile block copolymers[J].China Adhesives,2011,20(3). |
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| Authors: | WANG Xiao-lu MA Xiao-yan SONG Chun-ying WANG Ying |
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| Abstract: | The synthetic processes for block copolymers with polyacrylonitrile(PAN) and their self-assembly in solution were reviewed.Mainly some common radical polymerization methods,including ATRP(atom transfer radical polymerization),RAFT(reversible addition-fragmentation chain transfer) polymerization,NMP(nitroxide radical polymerization),CMRP(cobalt-mediated radical polymerization) and so on,were overviewed.Meanwhile,self-assembly of PAN block copolymers in solution was also summarized.Finally,some existent technic problems in these two aspects were proposed,and their future development direction was expected. |
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| Keywords: | acrylonitrile(AN) block copolymer radical polymerization self-assembly |
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