| 丙基脲硅胶毛细管整体柱的制备及性能研究 |
| |
| 引用本文： | 叶芳贵,黄保军,赵书林.丙基脲硅胶毛细管整体柱的制备及性能研究[J].分析测试学报,2009,28(11). |
| |
| 作者姓名： | 叶芳贵 黄保军 赵书林 |
| |
| 作者单位： | 广西师范大学,化学化工学院,药用资源化学与药物分子工程教育部重点实验室,广西,桂林,541004 |
| |
| 基金项目： | 广西应用基础研究专项资助项目，药用资源化学与药物分子工程教育部重点实验室主任基金资助项目，广西环境工程与保护评价重点实验室开放基金资助项目，广西研究生教育创新计划资助项目 |
| |
| 摘 要： | 采用溶胶-凝胶技术在毛细管中原位合成硅胶整体柱,通过表面化学修饰技术制备了极性的丙基脲硅胶整体柱.对所制备的整体柱柱性能进行了评价,考察了极性物质在该整体柱上的保留行为,并对其可能的保留机理进行了探讨.研究表明,该柱在亲水作用电色谱模式下能有效分离苯酚类极性小分子化合物.
|
| 关 键 词： | 溶胶-凝胶 硅胶整体柱 亲水作用 毛细管电色谱 |
Preparation and Characterization of 3-Ureidopropyl Silica Monolithic Column for Capillary Electrochromatography |
| |
| Abstract: | A polar propylurea silica capillary monolith was prepared by in-situ synthesizing in fused-silica capillary by sol - gel process and subsequent a chemical modification. The prepared monolithic silica column performance was evaluated. The electrochromatographic retention behaviors of model polar solutes were investigated and the retention mechanism was also discussed. The result also indicated that the monolithic silica columns could effectively separate polar phenols under hydrophilic interaction - capillary electrochromatography ( HI ?CEC) mode. |
| |
| Keywords: | sol - gel silica monolithic column hydrophilic interaction capillary electrochromatography |
| 本文献已被 万方数据 等数据库收录！ |
|
