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Synthesis and structure of Meisenheimer adducts in nucleophilic aromatic amination of 4,6-dinitrobenzofuroxan
Authors:I. V. Galkina  G. L. Takhautdinova  E. V. Tudrii  L. M. Yusupova  D. B. Krivolapov  I. A. Litvinov  R. A. Cherkasov  V. I. Galkin
Affiliation:1299. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia
2299. Kazan National Research Technological University, ul. Karla Marksa 68, Kazan, 420015, Tatarstan, Russia
3299. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia
Abstract:Stable crystalline σ-complexes (Meisenheimer adducts) were isolated for the first time in the reactions of superelectrophilic 4,6-dinitrobenzofuroxan with dodecyl- and hexadecylamines, and their structure was determined by X-ray analysis.
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