| 乙炔氢氯化反应铜基催化剂研究进展 |
| |
| 引用本文： | 邵艳秋,姜封庆,孙玺,常玉莹,王星月,宋冰,黄家辉.乙炔氢氯化反应铜基催化剂研究进展[J].塑料工业,2021(3):27-31,53. |
| |
| 作者姓名： | 邵艳秋 姜封庆 孙玺 常玉莹 王星月 宋冰 黄家辉 |
| |
| 作者单位： | 牡丹江师范学院化学化工学院;黑龙江省新型碳基功能与超硬材料重点实验室;中国科学院大连化学物理研究所 |
| |
| 基金项目： | 牡丹江师范学院科研项目(kjcx2019-98mdjnu);黑龙江省省属高等学校基本科研业务费科研机构专项(1355JG015);牡丹江师范学院省级大学生创新创业训练计划项目(202010233080)。 |
| |
| 摘 要： | 开发乙炔氢氯化无汞催化剂对我国聚氯乙烯(PVC)工业具有重要意义,目前以金为代表的贵金属催化剂已经接近工业化应用,但其生产成本高限制了其市场推广,因此相对价廉的铜基催化剂受到广泛关注。主要从配体和载体改性等方面综述了科研人员对金属铜基催化剂在乙炔氢氯化反应中性能提升所做的工作,并且总结了含铜多金属催化剂在乙炔氢氯化反应中的研究进展,最后对铜催化剂工业发展前景进行了展望。
|
| 关 键 词： | 乙炔氢氯化 非贵金属 铜基催化剂 载体 |
Research Progress of Copper Based Catalysts for Acetylene Hydrochlorination |
| |
| SHAO Yan-qiu,JIANG Feng-qing,SUN Xi,CHANG Yu-ying,WANG Xing-yue,SONG Bing,HUANG Jia-hui.Research Progress of Copper Based Catalysts for Acetylene Hydrochlorination[J].China Plastics Industry,2021(3):27-31,53. |
| |
| Authors: | SHAO Yan-qiu JIANG Feng-qing SUN Xi CHANG Yu-ying WANG Xing-yue SONG Bing HUANG Jia-hui |
| |
| Affiliation: | (Department of Chemistry Mudanjiang Normal University,Mudanjiang 157011,China;Key Laboratory of New Carbon-Based Functions and Superhard Materials,Mudanjiang 157011,China;Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China) |
| |
| Abstract: | The development of mercury-free acetylene hydrochlorination catalysts had great significance to Chinese polyvinyl chloride(PVC)industry.At present,precious metal catalysts represented by gold were chosen for industrial applications,but their high production costs limited their market promotion,therefore,relatively inexpensive copper-based catalysts had attracted widely attention.The performance improvement of metal copper-based catalysts in the hydrochlorination of acetylene was reviewed from the aspects of ligand and carrier modification.And the research progress of copper-containing multimetal catalysts in the hydrochlorination of acetylene were summarized,and finally the industrial development prospects of copper catalysts were prospected. |
| |
| Keywords: | Acetylene Hydrogen Chloride Non Noble Metal Copper-based Catalyst Support |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
