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溶聚丁苯橡胶连续聚合工艺
引用本文:刘美瑜,闫冰,邰峰,吕万树,史工昌.溶聚丁苯橡胶连续聚合工艺[J].石化技术,2006,13(2):62-66.
作者姓名:刘美瑜  闫冰  邰峰  吕万树  史工昌
作者单位:1. 中国石油化工股份有限公司北京燕山分公司研究院,北京,102500
2. 大连理工大学化工学院高分子材料系,大连,116012
摘    要:概述了溶聚丁苯橡胶连续聚合工艺的凝胶抑制技术.指出连续聚合丁艺的重点是确定合适的抑凝体系;N,N,N',N’-四甲基乙烯基二胺/1,2-丁二烯以及四氢呋喃/1,2-丁二烯是最常用的抑凝体系。综述了单釜连续聚合和多釜串联连续聚合工艺.对世界各大橡胶公司的连续聚合反应釜的结构进行了介绍。

关 键 词:溶聚丁苯橡胶  连续聚合工艺  凝胶抑制剂  聚合反应器
收稿时间:2005-12-26
修稿时间:2006-03-21

Continuous Polymerization Processes of SSBR
Liu Meiyu,Yan Bing,Tai Feng,Lü Wanshu,Shi Gongchang.Continuous Polymerization Processes of SSBR[J].Petrochemical Industry Technology,2006,13(2):62-66.
Authors:Liu Meiyu  Yan Bing  Tai Feng  Lü Wanshu  Shi Gongchang
Abstract:This paper summarized gel inhibiting technology in continuous polymerization process of solution polymerized styrene-butadiene rubber (SSBR), indicated that the main key is selecting proper gel inhibiting system and pointed out that the most common use gel inhibitors are TMEDA/1,2-Bd and THF/1,2-Bd. This paper also reviewed single reactor and multi -reactor processes and introduced structure of reactors in worldwide outstanding rubber corporations.
Keywords:solution polymerized styrene-butadiene rubber  continuous polymerization process  gel inhibitor  polymerization reactor
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