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Evidence for cyclopropene formation in the reactions of 4,4-dimethyl-4-silacyclohexadienylidene
Authors:Brian Coleman  Maitland Jones
Affiliation:Department of Chemistry, Princeton University Princeton, New Jersey 08540 U.S.A.
Abstract:In the reactions of 4,4-dimethylcyclohexadienylidene no evidence for cyclopropene formation has been found. By contrast, 4,4-dimethyl-4-silacyclohexadienylidene yields a product on reaction with butadiene that is best rationalized by intramolecular cyclopropene formation.
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