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Total synthesis of attenols A and B |
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| Authors: | B.V. Subba Reddy B. Phaneendra ReddyN. Swapnil J.S. Yadav |
| Affiliation: | Natural Products Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | A concise approach for the total synthesis of attenols A and B is described involving MacMillan’s α-aminooxylation, Evan’s asymmetric alkylation, Brown’s allylation, and spiro-ketalization as key steps. This approach has successfully demonstrated the α-aminooxylation protocol for the construction of the anti-1,3-diol unit. |
| Keywords: | Asymmetric alkylation Brown&rsquo s allylation MacMillan&rsquo s aminooxylation 1,3-Diols Spiro-ketalization |
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