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功能化有序介孔二氧化硅材料在分析样品前处理中的应用
引用本文:周婵娟,杜卓,李攻科.功能化有序介孔二氧化硅材料在分析样品前处理中的应用[J].中国无机分析化学,2011,1(2):20-30.
作者姓名:周婵娟  杜卓  李攻科
作者单位:中山大学化学与化学工程学院,广州 510257;中山大学化学与化学工程学院,广州 510257;中山大学化学与化学工程学院,广州 510257
基金项目:国家自然科学基金(No.20775095,No.20705042和No.90817012)、广东省自然科学基金(No. 9251027501000004)
摘    要:功能化有序介孔二氧化硅材料具有均一可调的介孔孔径、规则的孔道、稳定的骨架结构、易于修饰的内表面和较高的比表面积、高的吸附容量等特性,可用于生物、医药、环境样品等复杂基体中痕量分析物的高选择性分离与富集,因此在样品前处理中的应用特别引人瞩目。文中简要介绍了功能化有序介孔二氧化硅材料的制备方法,综述了功能化有序介孔二氧化硅材料在分离富集金属离子、有机污染物以及生物大分子样品前处理中的应用进展。

关 键 词:功能化  有序介孔二氧化硅材料  样品前处理
收稿时间:5/3/2011 12:00:00 AM
修稿时间:2011/5/13 0:00:00

Application of Functionalized Ordered Mesoporous Sillica Materials on Sample Pretreatment for Chemical Analysis
ZHOU Chanjuan,DU Zhuo and LI Gongke.Application of Functionalized Ordered Mesoporous Sillica Materials on Sample Pretreatment for Chemical Analysis[J].Chinese Journal of Inorganic Analytical Chemistry,2011,1(2):20-30.
Authors:ZHOU Chanjuan  DU Zhuo and LI Gongke
Affiliation:School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275, China;School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275, China;School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275, China
Abstract:Functionalized ordered mesoporous sillica materials have uniform and adjustable pore diameters, regular pore channels, stable skeleton structures, easily modified inner surfaces, relative high specific surface area and high adsorption capacity, etc. They can be used for selective separation and enrichment of trace analytes in complicated samples of biology, medicine and environment. Thus, functionalized Ordered Mesoporous Sillica Materials are gained special attention for sample pretreatment application. This review gives an introduction to preparation of functionalized mesoporous silica materials and an overview of their applications on separation and enrichment of mental ions, sample pretreatments for organic pollutants and biomacromolecules.
Keywords:functionalization  ordered mesoporous silica materials  sample pretreatment
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