| 三乙二醇二缩水甘油醚的合成 |
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| 引用本文： | 王培,王念贵,李陵岚,叶楚平. 三乙二醇二缩水甘油醚的合成[J]. 热固性树脂, 2006, 21(4): 21-22 |
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| 作者姓名： | 王培 王念贵 李陵岚 叶楚平 |
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| 作者单位： | 湖北大学化学与材料科学学院,湖北,武汉,430062;湖北大学化学与材料科学学院,湖北,武汉,430062;湖北大学化学与材料科学学院,湖北,武汉,430062;湖北大学化学与材料科学学院,湖北,武汉,430062 |
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| 摘 要： | 以三乙二醇和环氧氯丙烷为原料、三氟化硼乙醚络合物为催化剂合成三乙二醇二缩水甘油醚。研究了催化剂、反应温度、反应时间对反应产率的影响,结果表明:催化剂用量大约在5份时,产物收率最大,继续增加用量对产率影响不大;反应温度在一定范围内升高,产率增加;环氧反应时间为3.5 h,产率最高,达到92.7%。
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| 关 键 词： | 三乙二醇二缩水甘油醚 合成 催化剂 反应温度 反应时间 |
| 文章编号： | 1002-7432（2006）04-0021-02 |
| 收稿时间： | 2006-02-05 |
| 修稿时间： | 2006-02-24 |
SYNTHESIS OF TRIETHYLENE GLYCOL DIGLYCIDYL ETHER |
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| WANG Pei,WANG Nian-gui,Li Ling-lan,Ye Chu-ping. SYNTHESIS OF TRIETHYLENE GLYCOL DIGLYCIDYL ETHER[J]. Thermosetting Resin, 2006, 21(4): 21-22 |
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| Authors: | WANG Pei WANG Nian-gui Li Ling-lan Ye Chu-ping |
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| Affiliation: | College of Chemistry and Material Science, Hubei University, Wuhan430062 , China |
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| Abstract: | In this paper,the triethylene glycol diglycidyl ether was synthesized with triethylene glycol and(epoxy) chloropropane,and trifluorideboron ether complex as catalyst.The factors of the production rate was studied.The results showed that the production rate was mainly affected by the catalyst,reaction temperature and reaction time.The yield was up to 92.7 perceat and its epoxide number was 0.573 eq/100 g.when the catalyst was 5 phr.reaction time was 3.5 h reaction teamperature was 85 ℃. |
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| Keywords: | triethylene glycol diglycidyl ether preparation catalyst reaction temperature reaction time rate of production. |
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